) 0₂ K EtO₂C L CO₂Et EtO₂C. EtO₂C M N Heating sulfone K generates, in equilibrium, butadiene L and sulfur dioxide. Provide a curly arrow mechanism to describe the formation of L from K and explain how, by experimental design, good yields of L may be obtained despite this reaction being reversible. i) As shown above, subsequent heating of L with trans-, or cis-butenedioic acid diethyl ester generates isomeric adducts M and N, respectively. Draw structures for M and N and explain how they are stereoselectively formed.

) 0₂ K EtO₂C L CO₂Et EtO₂C. EtO₂C M N Heating sulfone K generates, in equilibrium, butadiene L and sulfur dioxide. Provide a curly arrow mechanism to describe the formation of L from K and explain how, by experimental design, good yields of L may be obtained despite this reaction being reversible. i) As shown above, subsequent heating of L with trans-, or cis-butenedioic acid diethyl ester generates isomeric adducts M and N, respectively. Draw structures for M and N and explain how they are stereoselectively formed.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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