.) This reaction occurs in large test tube at 32.0 ° C: 2 Al (s) +3 H2SO4 (aq) → 6 H2 (g) + Al2 (SO4) 3 (aq) A tube going through the stopper of the test tube feeds into a graduated cylinder that has been inverted in a tub of water. At the end of the reaction, the total pressure of gas in the inverted cylinder is 435. torr, and the volume of gas collected is 455. mL. What mass of aluminum must have reacted?
Ideal and Real Gases
Ideal gases obey conditions of the general gas laws under all states of pressure and temperature. Ideal gases are also named perfect gases. The attributes of ideal gases are as follows,
Gas Laws
Gas laws describe the ways in which volume, temperature, pressure, and other conditions correlate when matter is in a gaseous state. The very first observations about the physical properties of gases was made by Robert Boyle in 1662. Later discoveries were made by Charles, Gay-Lussac, Avogadro, and others. Eventually, these observations were combined to produce the ideal gas law.
Gaseous State
It is well known that matter exists in different forms in our surroundings. There are five known states of matter, such as solids, gases, liquids, plasma and Bose-Einstein condensate. The last two are known newly in the recent days. Thus, the detailed forms of matter studied are solids, gases and liquids. The best example of a substance that is present in different states is water. It is solid ice, gaseous vapor or steam and liquid water depending on the temperature and pressure conditions. This is due to the difference in the intermolecular forces and distances. The occurrence of three different phases is due to the difference in the two major forces, the force which tends to tightly hold molecules i.e., forces of attraction and the disruptive forces obtained from the thermal energy of molecules.
Reaction:
2 Al (s) + 3 H2SO4 (aq) → 6 H2 (g) + Al2(SO4)3 (aq)
Use an ideal gas equation to solve for the moles of H2 gas evolved,
PV = nRT
n = PV/RT
Given that,
Total pressure of the gas = P = 435 torr = (435torr / 760torr) x 1atm = 0.5724 atm
Volume of the gas collected = V = 455mL = 0.455 L
Temperature = 32oC = 32+273.15 = 305.15 K
R = 0.082057 L atm mol-1K-1
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