GENERAL CHEMISTRY(LL)-W/MASTERINGCHEM.
11th Edition
ISBN: 9780134566030
Author: Petrucci
Publisher: PEARSON
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Chapter 9, Problem 79SAE
Write electron configurations to show the first two ionizations for Cs. Explain why the second ionization energy is much greater than the first.
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Diels Alder Cycloaddition: Focus on regiochemistry (problems E-F) –> match + of thedienophile and - of the diene while also considering stereochemistry (endo).
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Chapter 9 Solutions
GENERAL CHEMISTRY(LL)-W/MASTERINGCHEM.
Ch. 9 - Prob. 1ECh. 9 - Suppose that lanthanum (Z = 57) were a newly...Ch. 9 - The following densities, in grams per cubic...Ch. 9 - The blowing melting points are in degrees Celsius....Ch. 9 - Mendeleev's periodic table did not preclude the...Ch. 9 - Prob. 6ECh. 9 - Prob. 7ECh. 9 - Concerning the incomplete seventh period of the...Ch. 9 - For each of the following pairs, indicate the atom...Ch. 9 - Indicate the smallest and the largest species...
Ch. 9 - Explain why the radii of atoms do not simply...Ch. 9 - The masses of individual atoms can be determined...Ch. 9 - Which is (a) the smallest atom in group 13; (b)...Ch. 9 - How would you expect the sizes of the hydrogen...Ch. 9 - Prob. 15ECh. 9 - Explain why the generalizations presented in...Ch. 9 - Among the following ions, several pairs are...Ch. 9 - Prob. 18ECh. 9 - All the isoelectronic species illustrated in the...Ch. 9 - Prob. 20ECh. 9 - Use principles established in this chapter to...Ch. 9 - Are there any atoms for which the second...Ch. 9 - Some electron affinities are negative quantities,...Ch. 9 - How much energy, in pules, must be absorbed to...Ch. 9 - How much energy, in kilojoules, is required to...Ch. 9 - Prob. 26ECh. 9 - The production of gaseous bromide ions from...Ch. 9 - Use ionization energies and electron affinities...Ch. 9 - The Naa ion and the Ne atom are isoelectronic. The...Ch. 9 - Prob. 30ECh. 9 - Compare the elements Al, Si, S, and Cl. a. Place...Ch. 9 - Compare the elements Na, Mg, O, and P. a. Place...Ch. 9 - Unpaired electrons are found in only one of the...Ch. 9 - Which of the following species has the greatest...Ch. 9 - Which of the following species would you expect to...Ch. 9 - Write electron configurations consistent with the...Ch. 9 - Must all atoms with an odd atomic number be...Ch. 9 - Neither Co24 nor Co24 has 4s electrons in its...Ch. 9 - Use ideas presented in this chapter to indicate...Ch. 9 - Arrange the following atoms in order of increasing...Ch. 9 - Arrange the following species in order of...Ch. 9 - For the following groups of elements, select the...Ch. 9 - Prob. 43ECh. 9 - Of the species Naa, Na, F, and F-, which has the...Ch. 9 - Match each of the lettered items on the left with...Ch. 9 - Prob. 46ECh. 9 - Which of the following ions are unlikely to be...Ch. 9 - Which of the following ions are likely to be found...Ch. 9 - Four atoms and/or ions are sketched below in...Ch. 9 - Prob. 50IAECh. 9 - In Mendeleev's time, indium oxide, which is 82.5%...Ch. 9 - Instead of accepting the atomic mass of indium...Ch. 9 - Refer to Figure 9-11 and explain why the...Ch. 9 - Explain why the third ionization energy of Li(g)...Ch. 9 - Prob. 55IAECh. 9 - Prob. 56IAECh. 9 - Studies done in 1880 showed that a chloride of...Ch. 9 - Assume that atoms are herd spheres, and use the...Ch. 9 - When sodium chloride is strongly heated in a...Ch. 9 - Use information from Chapters 8 and 9 to calculate...Ch. 9 - Refer only to the periodic table on the inside...Ch. 9 - Refer to the footnote on page 393. Then use values...Ch. 9 - Prob. 63IAECh. 9 - Prob. 64IAECh. 9 - The work functions for a number of metals are...Ch. 9 - The following are a few elements and their...Ch. 9 - Gaseous sodium atoms absorb quanta with the...Ch. 9 - A method for estimating electron affinities is to...Ch. 9 - We have seen that the wave functions of...Ch. 9 - In your own words, define the following terms (a)...Ch. 9 - Briefly describe each of the following ideas or...Ch. 9 - Explain the important distinctions between each...Ch. 9 - Prob. 73SAECh. 9 - Prob. 74SAECh. 9 - Prob. 75SAECh. 9 - Prob. 76SAECh. 9 - Prob. 77SAECh. 9 - An ion that is isoelectronic with Se2- is (a) S2-...Ch. 9 - Write electron configurations to show the first...Ch. 9 - Explain why the first ionization energy of Mg is...Ch. 9 - Prob. 81SAECh. 9 - Prob. 82SAECh. 9 - Find three pairs of elements that are out of order...Ch. 9 - Prob. 84SAECh. 9 - Prob. 85SAECh. 9 - Prob. 86SAECh. 9 - Prob. 87SAECh. 9 - Prob. 88SAECh. 9 - In multielectron atoms many of the periodic trends...Ch. 9 - Consider a nitrogen atom in the ground state and...Ch. 9 - Prob. 91SAECh. 9 - Describe how the ionization energies of the ions...Ch. 9 - Prob. 93SAECh. 9 - Prob. 94SAECh. 9 - When compared to a nonmetal of the same period, a...Ch. 9 - Prob. 96SAECh. 9 - Which of the following has a smaller radius than a...Ch. 9 - Prob. 98SAECh. 9 - The electrons lost when Fe ionizes to Fe2- are (a)...Ch. 9 - Prob. 100SAE
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- Question 4 Determine the rate order and rate constant for sucrose hydrolysis. Time (hours) [C6H12O6] 0 0.501 0.500 0.451 1.00 0.404 1.50 0.363 3.00 0.267 First-order, k = 0.210 hour 1 First-order, k = 0.0912 hour 1 O Second-order, k = 0.590 M1 hour 1 O Zero-order, k = 0.0770 M/hour O Zero-order, k = 0.4896 M/hour O Second-order, k = 1.93 M-1-hour 1 10 ptsarrow_forwardDetermine the rate order and rate constant for sucrose hydrolysis. Time (hours) [C6H12O6] 0 0.501 0.500 0.451 1.00 0.404 1.50 0.363 3.00 0.267arrow_forwardDraw the products of the reaction shown below. Use wedge and dash bonds to indicate stereochemistry. Ignore inorganic byproducts. OSO4 (cat) (CH3)3COOH Select to Draw ઘarrow_forward
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