EBK GENERAL CHEMISTRY
11th Edition
ISBN: 9780134419022
Author: Bissonnette
Publisher: PEARSON CUSTOM PUB.(CONSIGNMENT)
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Chapter 8, Problem 44E
Although Einstein made some early contributions to quantum theory, he was never able to accept the Heisenberg uncertainty principle, Hestated, "God does not play dice with the Universe." What do you suppose Einstein meant by this remark? In reply to Einstein's remark, Niels Bohr is supposed to have said, "Albert, stop telling God what to do." What do you suppose Bohr meant by this remark?
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There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS).
Ca, ppm
V, ppm
SCa, arb. units
SV, arb. units
20.0
10.0
14375.11
14261.02
40.0
10.0
36182.15
17997.10
60.0
10.0
39275.74
12988.01
80.0
10.0
57530.75
14268.54
100.0…
A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C.
H₂O(g) + C₁₂O(g) = 2 HOCl(g)
K = 0.0900 at 25°C
с
Calculate the equilibrium concentrations of each gas at 25 °C.
[H₂O]=
[C₁₂O]=
[HOCI]=
M
Σ
M
What units (if any) does the response factor (K) have? Does the response factor (K) depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)?
Chapter 8 Solutions
EBK GENERAL CHEMISTRY
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Show that the probability of finding a 2p,...Ch. 8 - Prob. 66ECh. 8 - Prepare a two-dimensional plot of Y(,) for the py...Ch. 8 - Prepare a two-dimensional plot of Yz(,) for the py...Ch. 8 - Using a graphical method, show that in a hydrogen...Ch. 8 - Use a graphical method or some other means to show...Ch. 8 - Identify the orbital that has (a) one radial node...Ch. 8 - Identify the orbital that has (a) two radial nodes...Ch. 8 - A contour map for an atomic orbital of hydrogen is...Ch. 8 - A contour map for an atomic orbital of hydrogen is...Ch. 8 - On the basis of the periodic table and rules for...Ch. 8 - Based on the relationship between electron...Ch. 8 - Which of the following is the correct orbital...Ch. 8 - Which of the following is the correct orbital...Ch. 8 - Use the basic rules for electron configurations to...Ch. 8 - Use orbital diagrams to show the distribution of...Ch. 8 - Prob. 81ECh. 8 - Without referring to any tables or listings in the...Ch. 8 - Which of the following electron configurations...Ch. 8 - Prob. 84ECh. 8 - Prob. 85ECh. 8 - Prob. 86ECh. 8 - The following electron configurations correspond...Ch. 8 - Prob. 88ECh. 8 - Derive the Balmer and Rydberg equations from...Ch. 8 - Prob. 90IAECh. 8 - The work function is the energy that must be...Ch. 8 - Infrared lamps are used in cafeterias to keep food...Ch. 8 - Prob. 93IAECh. 8 - Determine the de Broglie wavelength of the...Ch. 8 - The Pfund series of the hydrogen spectrum has as...Ch. 8 - Between which two levels of the hydrogen atom must...Ch. 8 - Prob. 97IAECh. 8 - Prob. 98IAECh. 8 - An atom in which just one of the outer-shell...Ch. 8 - If all other rules governing electron...Ch. 8 - Ozone, O2, absorbs ultraviolet radiation and...Ch. 8 - Radio signals from Voyager 1 in the 1970s were...Ch. 8 - Prob. 103IAECh. 8 - The angular momentum of an electron in the Bohr...Ch. 8 - Prob. 105IAECh. 8 - Prob. 106IAECh. 8 - Using the relationships given in Table 8.2, find...Ch. 8 - Prob. 108IAECh. 8 - Prob. 109IAECh. 8 - Prob. 110IAECh. 8 - In the ground state of a hydrogen atom, what is...Ch. 8 - 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