Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 7, Problem 44PP

(a)

Interpretation Introduction

Interpretation: The protic and aprotic nature for the given solvents should be classified.

Concept Introduction:

Protic solvent: solvents that contains H+ bonded to electronegative atom.

Aprotic solvent: they do not contain H+ directly bonded to the electronegative atom.

Electronegativity: it is the ability of atom to attract a lone pair of electrons towards itself in a substrate. Electronegativity property follows the trend that it increases across the periods and decreases down the column in the periodic table.

(b)

Interpretation Introduction

Interpretation: The protic and aprotic nature for the given solvents should be classified.

Concept Introduction:

Protic solvent: solvents that contains H+ bonded to electronegative atom.

Aprotic solvent: they do not contain H+ directly bonded to the electronegative atom.

Electronegativity: it is the ability of atom to attract a lone pair of electrons towards itself in a substrate. Electronegativity property follows the trend that it increases across the periods and decreases down the column in the periodic table.

(c)

Interpretation Introduction

Interpretation: The protic and aprotic nature for the given solvents should be classified.

Concept Introduction:

Protic solvent: solvents that contains H+ bonded to electronegative atom.

Aprotic solvent: they do not contain H+ directly bonded to the electronegative atom.

Electronegativity: it is the ability of atom to attract a lone pair of electrons towards itself in a substrate. Electronegativity property follows the trend that it increases across the periods and decreases down the column in the periodic table.

(d)

Interpretation Introduction

Interpretation: The protic and aprotic nature for the given solvents should be classified.

Concept Introduction:

Protic solvent: solvents that contains H+ bonded to electronegative atom.

Aprotic solvent: they do not contain H+ directly bonded to the electronegative atom.

Electronegativity: it is the ability of atom to attract a lone pair of electrons towards itself in a substrate. Electronegativity property follows the trend that it increases across the periods and decreases down the column in the periodic table.

(e)

Interpretation Introduction

Interpretation: The protic and aprotic nature for the given solvents should be classified.

Concept Introduction:

Protic solvent: solvents that contains H+ bonded to electronegative atom.

Aprotic solvent: they do not contain H+ directly bonded to the electronegative atom.

Electronegativity: it is the ability of atom to attract a lone pair of electrons towards itself in a substrate. Electronegativity property follows the trend that it increases across the periods and decreases down the column in the periodic table.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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