Consider 1 mole of supercooled water at -10°C. Calculate the entropy change of the water when the supercooled water freezes at -10°C and 1 atm. Useful data: Cp (ice) = 38 J mol-1 K-1 Cp (water) 75J mol −1 K -1 Afus H (0°C) 6026 J mol −1 Assume Cp (ice) and Cp (water) to be independent of temperature.

The molar enthalpy of vaporization of benzene at its normal boiling point (80.09°C) is 30.72 kJ/mol. Assuming that AvapH and AvapS stay constant at their values at 80.09°C, calculate the value of AvapG at 75.0°C, 80.09°C, and 85.0°C. Hint: Remember that the liquid and vapor phases will be in equilibrium at the normal boiling point.

3. The entropy of an ideal gas is S = Nkg In V. Entropy is a state function rather than a path function, and in this problem, you will show an example of the entropy change for an ideal gas being the same when you go between the same two states by two different pathways. A. Express ASV = S2 (V2) - S₁(V1), the change in entropy upon changing the volume from V₁to V2, at fixed particle number N and energy, U. B. Express ASN = S₂(N₂) - S₁ (N₁), the change in entropy upon changing the particle number from N₁ to N2, at fixed volume V and energy U. C. Write an expression for the entropy change, AS, for a two-step process (V₁, N₁) → (V2, N₁) → (V2, N₂) in which the volume changes first at fixed particle number, then the particle number changes at fixed volume. Again, assume energy is constant.