FUND OF ENG THERMODYN(LLF)+WILEYPLUS
9th Edition
ISBN: 9781119391777
Author: MORAN
Publisher: WILEY
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Problem 2: Entropy changes in free expansion and mixing.
A. An isolated box has a partition dividing it into two equal parts, each with a
volume V. Initially there are a total of N gas molecules all in the right-hand
partition of the box. An opening is made on the partition.
1. What property (N, U, etc.) of the gas is changing as the gas expands into the
left partition?
V >. N.
2. Calculate, in terms of N and V only, the change in volumetric entropy ASvol Sf-S of the gas
after it expands to fill both partitions.
3. Assume that each molecule has f degrees of freedom and that each begins with q energy blocks.
What is the change in the energetic entropy, in terms of N and q? What is the total change in
entropy of the gas?
4. Assume that the expanding gas is mol of CO2, each molecule with q = 12 energy blocks. Find
the change in entropy of the gas, in J/K, after it expands.
P.1
TOPIC: PROPERTIES OF SUBSTANCES:
Note: The pressure values are absolute values unless specified.
Determine the properties of H2O with units according to the following Table:
Sketch of location of point
in TS diagram below using
P, T and x lines as
applicable
CONDITIONS:
1. Liquid at P = 20 Mpa and T=
190 C
2. Saturated liquid at T = 223.75
deg C
3. Steam with quality of 90 % at
P = 6.7 Mpa
4. Dry steam at P = 18.05 Mpa
5. Steam at T =167 C, moisture =
3%
6. Steam with P = 3.42 Mpa and
T = 460 C
7. Steam at 17.398675 Mpa
gage, T=454.75 C
8. Steam at P = 17.0 Mpa, deg
SH = 60 C
9. Saturated vapor at 40 bars
10. Boiling Point of H2O in deg
Celsius at atmospheric
pressure of 0.19 Mpa
;
ANSWERS:
h =
V =
U=
S=
h =
U=
S=
h =
U=
S=
h =
U=
V =
U=
V=
h =
S=
T boiling point =
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