EBK GENERAL CHEMISTRY
11th Edition
ISBN: 9780134419022
Author: Bissonnette
Publisher: PEARSON CUSTOM PUB.(CONSIGNMENT)
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Chapter 6, Problem 27E
What is the volume, in liters, occupied by 89.2 g CO2(g) at 37 °C and 98.3 kPa?
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There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS).
Ca, ppm
V, ppm
SCa, arb. units
SV, arb. units
20.0
10.0
14375.11
14261.02
40.0
10.0
36182.15
17997.10
60.0
10.0
39275.74
12988.01
80.0
10.0
57530.75
14268.54
100.0…
A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C.
H₂O(g) + C₁₂O(g) = 2 HOCl(g)
K = 0.0900 at 25°C
с
Calculate the equilibrium concentrations of each gas at 25 °C.
[H₂O]=
[C₁₂O]=
[HOCI]=
M
Σ
M
What units (if any) does the response factor (K) have? Does the response factor (K) depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)?
Chapter 6 Solutions
EBK GENERAL CHEMISTRY
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The "initial"...Ch. 6 - Two evacuated bubs of equal volume are connected...Ch. 6 - Prob. 95IAECh. 6 - A 0.7178 g sample of a hydrocarbon occupies a...Ch. 6 - Prob. 97IAECh. 6 - Ammonium nitrite, NH4NO2,decomposes according to...Ch. 6 - A mature of 100 g H2 and 860 g O2, introduced into...Ch. 6 - Prob. 100IAECh. 6 - What is the partial pressure of CI2(g) , in...Ch. 6 - Prob. 102IAECh. 6 - When working with a mixture of gases, it is...Ch. 6 - Prob. 104IAECh. 6 - Gas cylinder A has e volume of 48.2 L and contains...Ch. 6 - Prob. 106IAECh. 6 - Producer gas is a type of fuel gas made by passing...Ch. 6 - Prob. 108IAECh. 6 - A mixture of H2(g) and O2(g) is prepared by...Ch. 6 - Prob. 110IAECh. 6 - Prob. 111IAECh. 6 - A breathing mixture is prepared which He is...Ch. 6 - Chlorine dioxide,CIO2, is sometimes used as a...Ch. 6 - The amount of ozone, O2,in a mixture of gases can...Ch. 6 - Prob. 115IAECh. 6 - Prob. 116IAECh. 6 - We have noted that atmospheric pressure depends on...Ch. 6 - Consider a sample ofO2(g) at 298 K and 1.0 atm....Ch. 6 - A nitrogen molecule (N2) having the average...Ch. 6 - Prob. 120IAECh. 6 - Prob. 121IAECh. 6 - Prob. 122IAECh. 6 - Prob. 123IAECh. 6 - A 0.156 g sample of magnesium-aluminum alloy...Ch. 6 - Prob. 125FPCh. 6 - Prob. 126FPCh. 6 - Prob. 127FPCh. 6 - Prob. 128FPCh. 6 - Prob. 129FPCh. 6 - Prob. 130SAECh. 6 - Briefly describe each concept or process: (a)...Ch. 6 - Prob. 132SAECh. 6 - Which exerts the greatest pressure. 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