Chapter 23, Problem 23.63P

(a)

Interpretation Introduction

Interpretation:

The type of isomerism given complex and its structure has to be drawn.

  $\left[Pt{(C{H}_{3}N{H}_2)}_{2}B{r}_2\right]$

Concept introduction:

Linkage isomers with different donor atoms from the same ligand bound to the metal ion,

Geometric isomers with differences in ligand arrangement relative to other ligands, and optical isomers with mirror images that are not superimposable.

(b)

Interpretation Introduction

Interpretation:

The type of isomerism given complex and its structure has to be drawn.

  $\left[Pt{(N{H}_3)}_{2}FCl\right]$

Concept introduction:

Linkage isomers with different donor atoms from the same ligand bound to the metal ion,

Geometric isomers with differences in ligand arrangement relative to other ligands, and optical isomers with mirror images that are not superimposable.

(c)

Interpretation Introduction

Interpretation:

The type of isomerism given complex and its structure has to be drawn.

  $\left[Pt(H_{2}O)(N{H}_3)FCl\right]$

Concept introduction:

Geometric isomers with differences in ligand arrangement relative to other ligands, and optical isomers with mirror images that are not superimposable.