(a)
Interpretation:
The plausible mechanism should be drawn for the following transformation.
Concept Introduction:
Imine formation:
Imine formation is formed when any primary
It requires an acid catalyst for fast reaction; otherwise this reaction is very slow.
The acid is needed for elimination of water molecule.
Proceeds Imine formation through six steps:-
1) Nucleophilic attack
2) Proton transfer
3) Proton transfer
4) Proton transfer
5) Loss of leaving group
6) Proton transfer
The protonated amines are usually called as ammonium ion.
Imine is popularly known as Schiff base.
To Draw: The following transformation of the plausible mechanism
(b)
Interpretation:
The plausible mechanism should be drawn for the following transformation.
Concept Introduction:
Imine formation:
Imine formation is formed when any primary amine reacts with an aldehydes or ketone under appropriate condition.
It requires an acid catalyst for fast reaction; otherwise this reaction is very slow.
The acid is needed for elimination of water molecule.
Proceeds Imine formation through six steps:-
1) Nucleophilic attack
2) Proton transfer
3) Proton transfer
4) Proton transfer
5) Loss of leaving group
6) Proton transfer
The protonated amines are usually called as ammonium ion.
Imine is popularly known as Schiff base.
To Draw: The following transformation of the plausible mechanism
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Chapter 19 Solutions
ORGANIC CHEMISTRY 2-SEMESTER-ACCESS
- Don't used hand raiting and don't used Ai solutionarrow_forward2' P17E.6 The oxidation of NO to NO 2 2 NO(g) + O2(g) → 2NO2(g), proceeds by the following mechanism: NO + NO → N₂O₂ k₁ N2O2 NO NO K = N2O2 + O2 → NO2 + NO₂ Ко Verify that application of the steady-state approximation to the intermediate N2O2 results in the rate law d[NO₂] _ 2kk₁[NO][O₂] = dt k+k₁₂[O₂]arrow_forwardPLEASE ANSWER BOTH i) and ii) !!!!arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
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