Chapter 19, Problem 19.12QAP

Problem 6-17 Look at the following energy diagram: Energy Reaction progress (a) Is AG for the reaction positive or negative? Label it on the diagram. (b) How many steps are involved in the reaction? (c) How many transition states are there? Label them on the diagram. Problem 6-19 What is the difference between a transition state and an intermediate? Problem 6-21 Draw an energy diagram for a two-step reaction with Keq > 1. Label the overall AG°, transition states, and intermediate. Is AG° positive or negative? Problem 6-23 Draw an energy diagram for a reaction with Keq = 1. What is the value of AG° in this reaction?

Problem 6-37 Draw the different monochlorinated constitutional isomers you would obtain by the radical chlorination of the following compounds. (b) (c) Problem 6-39 Show the structure of the carbocation that would result when each of the following alkenes reacts with an acid, H+. (a) (b) (c)

Please draw the major product of this reaction. Ignore inorganic byproducts and the carboxylic side product

Please draw the major product of this reaction.

Draw the major product of this reaction.

identify the carbonyl compound that is incapable of forming an enolate ion

predict the product formed by the reaction of one mole each of cyclohex-2-en-1-one and lithium diethylcuprate. Assume a hydrolysis step follows the addition

Please handwriting for questions 1 and 3

Is (CH3)3NHBr an acidic or basic salt? What happens when dissolved in aqueous solution? Doesn't it lose a Br-? Does it interact with the water? Please advise.