ORGANIC CHEMISTRY-ACCESS PACKAGE
ORGANIC CHEMISTRY-ACCESS PACKAGE
4th Edition
ISBN: 9781119833130
Author: Klein
Publisher: WILEY
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Is nucleophilic acyl substitution an SN1 or SN2 reaction?
Draw product A, indicating what type of reaction occurs. NH2 F3C CF3 NH OMe NH2-NH2, ACOH A
Photochemical smog is formed in part by the action of light on nitrogen dioxide. The wavelength of radiation absorbed by NO2 in this reaction is 197 nm.(a) Draw the Lewis structure of NO2 and sketch its π molecular orbitals.(b) When 1.56 mJ of energy is absorbed by 3.0 L of air at 20 °C and 0.91 atm, all the NO2 molecules in this sample dissociate by the reaction shown. Assume that each absorbed photon leads to the dissociation (into NO and O) of one NO2 molecule. What is the proportion, in parts per million, of NO2 molecules in this sample? Assume that the sample behaves ideally.
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