Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
9th Edition
ISBN: 9781292151229
Author: Wade, LeRoy G.
Publisher: PEARSON
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Textbook Question
Chapter 15.10, Problem 15.13P
Show how you might synthesize the following compounds starting with bromobenzene, and alkyl or alkenyl halides of four carbon atoms or fewer.
- a. 3-phenylprop-1-ene
- b. 5-methylhex-2-ene
- c. *dec-5-ene
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Draw the structure of the following compounds.
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A student was given the structural formulas of several compounds and was asked to give them systematic names. How many did the student name correctly? Correct those that are misnamed. a. 4-bromo-3-pentanol b. 2,2-dimethyl-4-ethylheptane c. 5-methylcyclohexanol d. 1,1-dimethyl-2-cyclohexanol e. 5-(2,2-dimethylethyl)nonane f. isopentylbromide g. 3,3-dichlorooctane h. 5-ethyl-2-methylhexane i. 1-bromo-4-pentanol j. 3-isopropyloctane k. 2-methyl-2-isopropylheptane l. 2-methyl-N,N-dimethyl-4-hexanamine
Consider the structure of cyclohexene, if it undergoes epoxidation followed by exposure to water, which of the following final product is formed?
a. Cyclohexan-1,2,-diol
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Chapter 15 Solutions
Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
Ch. 15.2 - Prob. 15.1PCh. 15.2 - Prob. 15.2PCh. 15.2 - Prob. 15.3PCh. 15.4 - Prob. 15.4PCh. 15.4 - Prob. 15.5PCh. 15.5 - Treatment of an alkyl halide with AgNO3 in alcohol...Ch. 15.5 - Propose a mechanism for each reaction, showing...Ch. 15.6 - When Br2 is added to buta-1,3-diene at 15 C, the...Ch. 15.7 - Prob. 15.9PCh. 15.7 - When N-bromosuccinimide is added to hex-1-ene in...
Ch. 15.7 - Prob. 15.11PCh. 15.9 - Addition of 1-bromobut-2-ene to magnesium metal in...Ch. 15.10 - Show how you might synthesize the following...Ch. 15.11 - Predict the products of the following proposed...Ch. 15.11 - Prob. 15.15PCh. 15.11A - Prob. 15.16PCh. 15.11B - Prob. 15.17PCh. 15.11B - Predict the products of the following Diels-Alder...Ch. 15.12C - Prob. 15.19PCh. 15.12C - Prob. 15.20PCh. 15.13C - Prob. 15.21PCh. 15.13D - Using the examples in Table15-2 to guide you,...Ch. 15.14 - Phenolphthalein is an acid-base indicator that is...Ch. 15 - Prob. 15.24SPCh. 15 - Prob. 15.25SPCh. 15 - Show how the reaction of an allylic halide with a...Ch. 15 - Prob. 15.27SPCh. 15 - A solution was prepared using 0.0010 g of an...Ch. 15 - Prob. 15.29SPCh. 15 - Prob. 15.30SPCh. 15 - Prob. 15.31SPCh. 15 - Prob. 15.32SPCh. 15 - Prob. 15.33SPCh. 15 - Give the structures of the products represented by...Ch. 15 - Furan and malemide undergo a Diels-Alder reaction...Ch. 15 - Prob. 15.36SPCh. 15 - Prob. 15.37SPCh. 15 - Prob. 15.38SPCh. 15 - Prob. 15.39SPCh. 15 - Determine whether each structure is likely to be...Ch. 15 - An important variation of the Diels-Alder reaction...
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- 12. Write structural formulas for the following alkene names. a. hept-2-ene b. hex-2-ene 6,7-dimethyloct-1-ene d. 2,4-dimethyloct-4-ene с. 3-ethylnon-2-ene е.arrow_forward9. Provide a systematic name for the following compound? A. 1,2,4-trimethyl-5-ethylcyclohexane B. 5-ethyl-1,2,4-trimethylcyclohexane C. 1-ethyl-2,4,5-trimethylcyclohexane D. 2,4,5-trimethyl-1-ethylcyclohexane 2 3arrow_forwardWhich among the following compounds has the most electronegative carbon in structure? a. benzaldehyde b. benzene c. cyclobutane d. butyne The radical substitution reaction is primarily observed in the following reactions. Which reaction is it? a. Oxidation of but-2-ene b. Boiling of hex-3-ene c. Chlorination of butane d. Combustion of methane Which among the following statements is FALSE about alkanes and cycloalkanes? a. all alkanes produce CO2 and water vapor upon complete combustion b. alkanes undergo substitution reactions c. the empirical formula of all alkanes is CnH2n+2 d. cyclic alkanes exhibit bond strain in the sp#-sp# sigma bondsarrow_forward
- 4. MAINIDEA Compare and contrast alkyl halides and aryl halides. 5. Draw structures for the following molecules. a. 2-chlorobutane c. 1,1,1-trichloroethane b. 1,3-difluorohexane d. 1-bromo-4-chlorobenzene 6. Define functional group and name the group present in each of the following structures. Name the type of organic compound each substance represents. a. CH3CH,CH2OH b. CH;CH,F c. CH;CH,NH2 7. Evaluate How would you expect the boiling points of propane and 1-chloropropane to compare? Explain your answer. d. CH3C- OH 8. Interpret Scientific Illustrations Examine the pair of substituted hydrocarbons illustrated at right, and decide whether it represents a pair of optical isomers. Explain your answer.arrow_forwardNOMENCLATURE, ANALYSIS & REACTIONSarrow_forward4- Choose the correct reactants required to synthesize the following molecule. H3CO OCH 3 A. Acetone and methanal B. Acetone and methanol C. Formaldehyde and propanal D. Formaldehyde and propanol 5- What is the IUPAC name of the following compound? CI A. 6-Chloro-4-ethoxy-1-octanal B. 6-Chloro-4-ethoxyoctanal C. 6-Chloro-4-ethoxycyclooctanal D. 4-Ethoxy-6-chlorooctanal - What is the IUPAC name of the following compound? 0 Br. Br Cl A. 2,6-Dibromo-3-chloro-5,5-dimethylhexanone B. 2,6-Dibromo-3-chloro-5,5-dimethylcyclohexanone C. 2,6-Dibromo-5-chloro-3,3-dimethylhexanone D. 2,6-Dibromo-5-chloro-3,3-dimethylcyclohexanonearrow_forward
- 1. Give the structure corresponding to each name. a. 4-ethyl-3-heptanol b. 3-chloro-1,2-propanediol c. diisobutyl ether d. 1,2-epoxy-1,3,3-trimethylcyclohexane e. 1-ethoxy-3-ethylheptanearrow_forwardA student was given the structural formulas of several compounds and was asked to give them systematic names. How many did she name correctly? Correct those that are misnamed. a. 4-ethyl-2-pentyne b. 2-methyl-3-hexyne c. 4-chloro-2-pentyne d. 2,3-dimethyl-5-octyne e. 4-heptynearrow_forwardHelparrow_forward
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How to Design a Total Synthesis; Author: Chemistry Unleashed;https://www.youtube.com/watch?v=9jRfAJJO7mM;License: Standard YouTube License, CC-BY