The statement that put incorrect interpretation with respect to the coupling of the proton that is present at C1 position of the geometrical isomers of 4 − t e r t − butylcyclohexanol is to be identified. Concept Introduction: The spectral line of a proton in an NMR spectrum is appreciably affected by the chemical environment of its neighboring proton. In NMR, it is observed that if a proton is surrounded by such protons that have different chemical environment then splitting of the NMR signal of that proton is taken place because of the spin-spin coupling of the proton with its neighboring protons.

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Answer 1

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Chapter 14, Problem 55DSP

Interpretation Introduction

Interpretation:

The statement that put incorrect interpretation with respect to the coupling of the proton that is present at C1 position of the geometrical isomers of 4−tert−butylcyclohexanol is to be identified.

Concept Introduction:

The spectral line of a proton in an NMR spectrum is appreciably affected by the chemical environment of its neighboring proton.

In NMR, it is observed that if a proton is surrounded by such protons that have different chemical environment then splitting of the NMR signal of that proton is taken place because of the spin-spin coupling of the proton with its neighboring protons.

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Answer 2

Question

Chapter 14, Problem 55DSP

Interpretation Introduction

Interpretation:

The statement that put incorrect interpretation with respect to the coupling of the proton that is present at C1 position of the geometrical isomers of 4−tert−butylcyclohexanol is to be identified.

Concept Introduction:

The spectral line of a proton in an NMR spectrum is appreciably affected by the chemical environment of its neighboring proton.

In NMR, it is observed that if a proton is surrounded by such protons that have different chemical environment then splitting of the NMR signal of that proton is taken place because of the spin-spin coupling of the proton with its neighboring protons.

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Answer 3

Question

Chapter 14, Problem 55DSP

Interpretation Introduction

Interpretation:

The statement that put incorrect interpretation with respect to the coupling of the proton that is present at C1 position of the geometrical isomers of 4−tert−butylcyclohexanol is to be identified.

Concept Introduction:

The spectral line of a proton in an NMR spectrum is appreciably affected by the chemical environment of its neighboring proton.

In NMR, it is observed that if a proton is surrounded by such protons that have different chemical environment then splitting of the NMR signal of that proton is taken place because of the spin-spin coupling of the proton with its neighboring protons.

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Answer 4

Question

Chapter 14, Problem 55DSP

Interpretation Introduction

Interpretation:

The statement that put incorrect interpretation with respect to the coupling of the proton that is present at C1 position of the geometrical isomers of 4−tert−butylcyclohexanol is to be identified.

Concept Introduction:

The spectral line of a proton in an NMR spectrum is appreciably affected by the chemical environment of its neighboring proton.

In NMR, it is observed that if a proton is surrounded by such protons that have different chemical environment then splitting of the NMR signal of that proton is taken place because of the spin-spin coupling of the proton with its neighboring protons.

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Answer 5

Chapter 14, Problem 55DSP

Interpretation Introduction

Interpretation:

The statement that put incorrect interpretation with respect to the coupling of the proton that is present at C1 position of the geometrical isomers of 4−tert−butylcyclohexanol is to be identified.

Concept Introduction:

The spectral line of a proton in an NMR spectrum is appreciably affected by the chemical environment of its neighboring proton.

In NMR, it is observed that if a proton is surrounded by such protons that have different chemical environment then splitting of the NMR signal of that proton is taken place because of the spin-spin coupling of the proton with its neighboring protons.

Answer 6

Chapter 14, Problem 55DSP

Interpretation Introduction

Interpretation:

The statement that put incorrect interpretation with respect to the coupling of the proton that is present at C1 position of the geometrical isomers of 4−tert−butylcyclohexanol is to be identified.

Concept Introduction:

The spectral line of a proton in an NMR spectrum is appreciably affected by the chemical environment of its neighboring proton.

In NMR, it is observed that if a proton is surrounded by such protons that have different chemical environment then splitting of the NMR signal of that proton is taken place because of the spin-spin coupling of the proton with its neighboring protons.

Answer 7

Chapter 14, Problem 55DSP

Interpretation Introduction

Interpretation:

The statement that put incorrect interpretation with respect to the coupling of the proton that is present at C1 position of the geometrical isomers of 4−tert−butylcyclohexanol is to be identified.

Concept Introduction:

The spectral line of a proton in an NMR spectrum is appreciably affected by the chemical environment of its neighboring proton.

In NMR, it is observed that if a proton is surrounded by such protons that have different chemical environment then splitting of the NMR signal of that proton is taken place because of the spin-spin coupling of the proton with its neighboring protons.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 14.3 - Prob. 1P Ch. 14.3 - Prob. 2P Ch. 14.4 - The 1H NMR signal for bromoform (CHBr3) appears at...Ch. 14.5 - identify the most shielded and least shielded...Ch. 14.5 - (a) Assign the chemical shifts 1.6, 2.2, and 4.8...Ch. 14.5 - Assign the chemical shifts 1.1, 1.7, 2.0, and 2.3...Ch. 14.5 - Assign the chemical shifts 1.6, 4.0, 7.5, 8.2, and...Ch. 14.6 - The 300-MHz 1H NMR spectrum of 1,4-dimethylbenzene...Ch. 14.6 - Prob. 9P Ch. 14.6 - How many signals would you expect to find in the...

Solution Summary: The author explains that the spectral line of a proton in an NMR spectrum is appreciably affected by the chemical environment of its neighboring protons.

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Chapter 14 Solutions