An elusive intermediate of atmospheric reactions of HONO may be nitrosyl O-hydroxide, HOON. Electronic structure calculations seem to indicate that HOON is best represented by a combination of three resonance structures, with major contribution from a radical-pair structure (involving HO and NO radicals), significant contribution from a molecular structure, and a small contribution from an ion-pair structure (involving HO – and NO + ions). Use the information to represent the structure of HOON in terms of these three resonance structures.
An elusive intermediate of atmospheric reactions of HONO may be nitrosyl O-hydroxide, HOON. Electronic structure calculations seem to indicate that HOON is best represented by a combination of three resonance structures, with major contribution from a radical-pair structure (involving HO and NO radicals), significant contribution from a molecular structure, and a small contribution from an ion-pair structure (involving HO – and NO + ions). Use the information to represent the structure of HOON in terms of these three resonance structures.
An elusive intermediate of atmospheric reactions of HONO may be nitrosyl O-hydroxide, HOON. Electronic structure calculations seem to indicate that HOON is best represented by a combination of three resonance structures, with major contribution from a radical-pair structure (involving HO and NO radicals), significant contribution from a molecular structure, and a small contribution from an ion-pair structure (involving
HO
–
and
NO
+
ions). Use the information to represent the structure of HOON in terms of these three resonance structures.
sketch the nature of the metal-alkylidene bonding interactions.
Part C
The perspective formula of isoleucine, an amino acid, is provided below.
HOOC
H₂NIC
H
川
CH3
CH,CH3
Draw the Newman projection in staggered conformation for isoleucine by viewing the molecule along the
C-2-C-3 bond.
1. Edit the Newman projection on the canvas.
2. Replace the appropriate hydrogens with the appropriate -CH3 or other groups.
3. If you need to start over, Undo or choose a Newman projection from the Templates toolbar
(bottom).
Important: Never delete the hydrogen atoms or bonds directly attached to the template, and do not move
them by dragging or dropping them. That will break the projections structures. Only replace them!
▸ View Available Hint(s)
0 2
H± 3D
EXP.
L
ד
י
CONT. 2
H
0
N
о
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INTRODUCTION TO MOLECULAR QUANTUM MECHANICS -Valence bond theory - 1; Author: AGK Chemistry;https://www.youtube.com/watch?v=U8kPBPqDIwM;License: Standard YouTube License, CC-BY