ORGANIC CHEMISTRY,SOLNS...-ETEXT+BOX
ORGANIC CHEMISTRY,SOLNS...-ETEXT+BOX
4th Edition
ISBN: 9781119760702
Author: Klein
Publisher: WILEY
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Chapter 11, Problem 43CP

The compound Z -3-hexenyl acetate is one of several volatile organic signaling compounds released from Arabidopsis leaves when they are damaged.10 Propose a synthesis of this compound using ethylene H 2 C = C H 2 and acetic acid C H 3 C O 2 H as your only sources of carbon atoms. Use the reaction described in Problem 11.33 as one of the steps of the synthesis. (Hint: See SkillBuilder 7.8.)

Chapter 11, Problem 43CP, The compound Z-3-hexenyl acetate is one of several volatile organic signaling compounds released

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Use solubility rules to provide balance molecular equation, total, and net ionic equation
Br HO ? HO ✓ OH
Use the literature Ka value of the acetic acid, and the data below to answer these questions. Note: You will not use the experimental titration graphs to answer the questions that follow.  Group #1:   Buffer pH = 4.35 Group #2: Buffer pH = 4.70 Group #3: Buffer pH = 5.00 Group #4: Buffer pH = 5.30 Use the Henderson-Hasselbalch equation, the buffer pH provided and the literature pKa value of acetic acid to perform the following: a) calculate the ratios of [acetate]/[acetic acid] for each of the 4 groups buffer solutions above. b) using the calculated ratios, which group solution will provide the best optimal buffer (Hint: what [acetate]/[acetic acid] ratio value is expected for an optimal buffer?) c) explain your choice
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How to Design a Total Synthesis; Author: Chemistry Unleashed;https://www.youtube.com/watch?v=9jRfAJJO7mM;License: Standard YouTube License, CC-BY