When halogenoalkanes are hydrolysed under reflux, a new compound A is formed. Compound A burns with a good supply of air it produces two products (compounds B and C). Further reaction of compound A with acidified K2Cr207 under reflux will give a new compound D. The functional group of compound D can be detected by adding a few drops of X reagent which gives a yellow/orange coloured precipitate. Further investigation revealed when compound D reacts with Tollen's reagent, the result is negative. However, the prolonged boiling with the oxidizing agent of compound D produces a new compound E and two side products (carbon dioxide and water). The reaction of compound E with solid PCl, produced a new compound F and released Y fumes. a) Identify the possible condensed structure of compound A, B, C, D, E and F. State the IUPAC name for each of the compound. b) Show the complete reaction for the formation of compounds B and C when compound A burns with a good supply of air. c) Propose the complete reaction of compound D when react with X reagent and state the reagent X. d) Explain why compound D will gives negative result with Tollen's reagent. e) Show the complete chemical equation of compound E from compound D.

When halogenoalkanes are hydrolysed under reflux, a new compound A is formed. Compound A burns with a good supply of air it produces two products (compounds B and C). Further reaction of compound A with acidified K2Cr207 under reflux will give a new compound D. The functional group of compound D can be detected by adding a few drops of X reagent which gives a yellow/orange coloured precipitate. Further investigation revealed when compound D reacts with Tollen's reagent, the result is negative. However, the prolonged boiling with the oxidizing agent of compound D produces a new compound E and two side products (carbon dioxide and water). The reaction of compound E with solid PCl, produced a new compound F and released Y fumes. a) Identify the possible condensed structure of compound A, B, C, D, E and F. State the IUPAC name for each of the compound. b) Show the complete reaction for the formation of compounds B and C when compound A burns with a good supply of air. c) Propose the complete reaction of compound D when react with X reagent and state the reagent X. d) Explain why compound D will gives negative result with Tollen's reagent. e) Show the complete chemical equation of compound E from compound D.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

Fill in the blanks
rate constants for the decomposition of an unstable cis-azoalkane are given below. -20.73 2.31 T (°C) k (10-4 s¹) -24.82 1.22 -17.02 4.39 -13.00 8.50 Calculate the enthalpy, entropy, and free energy of activation at -20.00 °C. -8.95 14.3
Compound A, C₁1 H160, was found to be an optically active alcohol. Despite its apparent unsaturation, no hydrogen was absorbed on catalytic reduction over a Pd/C catalyst. On treatment of A with dilute H₂SO4, dehydration occurred and an optically inactive alkene B, C₁₁H₁4 was produced as the major product. Alkene B, on ozonolysis, gave two products. Product C, C7H6O, was shown to be an aldehyde while product D, C4H8O, was shown to be a ketone. Draw the structure of compound C. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one.
In addition to more highly fluorinated products, fluorination of 2-methylbutane yields a mixture of compounds with the formula C5H10F2. Draw the structures of all the isomers with the formula C5H10F2 that would be produced and label with a star all the chiral centers present in their structures.
Calculate the units of unsaturation of C6H7NO. And draw out the structure.
Give the structure of the following compound(a) 3-bromo-2-methylpentane
Please don't provide handwritten solution ....
Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry. If the product is racemic write racemic or draw both isomers. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state "No Reaction"
How many monobrominated isomers are expected when 2-methylpentane reacts with Br2 in the presence of light O 5 O 3 4 O 2
INSTRUCTIONS: Choose from the options A-E and explain briefly by illustrations the chemistry behind each answer. Preamble: A reaction flask contains a 2-bromopentane in an ethanolic solution of sodium ethoxide at room temperature and results in the formation of two olefinic products. Predict the products that would be formed from such a reaction a)1-pentene (80%) and 2-pentene (20%)B)1-pentene (20%) and 2-pentene (80 %)C)1-pentene (50 %) and 2-pentene (50 %)D)1-pentene (0 %) and 2-pentene (100 %)E)1-pentene (100 %) and 2-pentene (0 %) What reaction pathway is followed by the reaction above?a)E2 dehydrohalogenation B)E1 dehydrohalogenationC)SN1 dehydrohalogenationD)SN2 dehydrohalogenation A mixture of E1 and E2 pathways What is responsible for the formation of different products (major and minor).A)The different activated complex involved in the mechanism. B)Bimolecular nuclephilic substitution reaction C)Bimolecular Elimination reaction D)The presence of sodium ethoxideE)The…
Name, draw and describe the organic product of the reaction between 2-methylbut-1-ene and H2O in the presence of H2SO4 and provide a clear rationale as to why this is the major product of the reaction.
Please don't provide handwriting solution