What are the symmetry numbers o for the foll i. 3"CI"Cl ii. 3"C1$Cl iii. Triangular H iv. All isomers of C2H2F2 v. CH;Cl vi. CH2C12 vii. C,H6

Biochemistry
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Publisher:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Chapter1: Biochemistry: An Evolving Science
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5. Consider rotational motion:
What are the symmetry numbers o for the following molecules:
i. 35C1"Cl
ii. 5CI*Cl
iii. Triangular H
а.
iv. All isomers of C2H2F2
v. CH;Cl
vi. CH2C12
vii. C,H6
b. At what temperature does the high temperature limit become valid for
i. DBr (B = 4.24 cm-1)
ii. F35 CI (B
iii. CsI (B = 0.0236 cm-1)
0.516 cm-1)
%3D
At the temperatures obtained for the molecules in part b. obtain Jmax and (J) for the
temperature obtained in b. and at 500K
С.
Transcribed Image Text:5. Consider rotational motion: What are the symmetry numbers o for the following molecules: i. 35C1"Cl ii. 5CI*Cl iii. Triangular H а. iv. All isomers of C2H2F2 v. CH;Cl vi. CH2C12 vii. C,H6 b. At what temperature does the high temperature limit become valid for i. DBr (B = 4.24 cm-1) ii. F35 CI (B iii. CsI (B = 0.0236 cm-1) 0.516 cm-1) %3D At the temperatures obtained for the molecules in part b. obtain Jmax and (J) for the temperature obtained in b. and at 500K С.
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