The following data were obtained in the construction of a calibration plot for the determination of ruthenium (VI) using a polarographic method: Ruthenium (VI) Concentration (μg/ml) Limiting Current (μA) 0 0 2 23.3 4 48.5 6 78.7 8 107.3 10 131.8 13 154.3 16 204.4 20 238.0 1.2702g of a dry solid sample containing an unknown amount of Ru6+ was dissolved in aqueous solution and made up to the 250ml mark. 20.0ml of this solution were further diluted to 50ml. A current reading of 151.2μA was obtained for this latter solution. Using a linear graphical method, calculate the percent-by-weight (%w/w) of Ru6+ in the unknown solid sample.   Can you show all the steps of the solution

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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The following data were obtained in the construction of a calibration plot for the determination of ruthenium (VI) using a polarographic method:

Ruthenium (VI) Concentration (μg/ml)

Limiting Current

(μA)

0

0

2

23.3

4

48.5

6

78.7

8

107.3

10

131.8

13

154.3

16

204.4

20

238.0

1.2702g of a dry solid sample containing an unknown amount of Ru6+ was dissolved in aqueous solution and made up to the 250ml mark. 20.0ml of this solution were further diluted to 50ml. A current reading of 151.2μA was obtained for this latter solution. Using a linear graphical method, calculate the percent-by-weight (%w/w) of Ru6+ in the unknown solid sample.

 

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