The analogous reaction of trans-1,2-dichloroethylene with benzyne produces the same cIS and trans- products but in a 0.230: 1 ratio. 1) Derive two expressions for the predicted cis: trans product ration starting from cis and trans- 1,2-dichloroethylene on the basis of the proposed mechanism. 2) Calculate the rate constant ration k1/k2 and k3/k-1 from the observed product

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The analogous reaction of trans-1,2-dichloroethylene with benzyne produces the same cis-
and trans- products but in a 0.230: 1 ratio.
1) Derive two expressions for the predicted cis: trans product ration starting from cis-
and trans- 1,2-dichloroethylene on the basis of the proposed mechanism.
2) Calculate the rate constant ration k1/k2 and k3/k-1 from the observed product
ratios.
Transcribed Image Text:The analogous reaction of trans-1,2-dichloroethylene with benzyne produces the same cis- and trans- products but in a 0.230: 1 ratio. 1) Derive two expressions for the predicted cis: trans product ration starting from cis- and trans- 1,2-dichloroethylene on the basis of the proposed mechanism. 2) Calculate the rate constant ration k1/k2 and k3/k-1 from the observed product ratios.
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