Organic compounds that contain large proportions of nitrogen and oxygen tend to be unstable and are easily decomposed. Hexanitroethane, C2(NO2)6, decomposes according to the equation C2(NO2)6– 2NO, + 4NO + 2CO; The reaction in CCI4 solvent is first order with respect to C2(NO2)6. At 63.7 °C, k = 0.000254 s'* and at 112.6°C, k = 0.0126s'!. (a) What is the half-life of C{NO2), at 63.7 °C? 1 seconds eTextbook and Media (b) What is the half-life of C2(NO2), at 112.6 °C? seconds (c) If0.100 mol of C2(NO2)6 is dissolved in CCI4 at 63.7°C to give 1.00 L of solution, what will be the C2(NO2)6 concentration after 50.0 minutes? A M

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Organic compounds that contain large proportions of nitrogen and oxygen tend to be unstable and are easily decomposed.
Hexanitroethane, C2(NO2)6, decomposes according to the equation
C2(NO2)6- 2NO, + 4NO + 2CO,
The reaction in CCl, solvent is first order with respect to Cz{NO2)s At 63.7°C, k= 0.000254 s* and at 112.6°C, k = 0.0126s*.
(a)
What is the half-life of C2{NO2); at 63.7 °C? i
seconds
e Textbook and Media
(b)
What is the half-life of C2(NO2)s at 112.6 °C?
seconds
(c)
IF0.100 mol of C2(NO2)6 is dissolved in CCI4 at 63.7°C to give 1.00 L of solution, what will be the C2(NO2), concentration after
50.0 minutes? i
M
(d)
What is the value of the activation energy of this reaction, expressed in kilojoules? i
kJ/mol
(e)
What is the rate constant at 159.4 °C?
Transcribed Image Text:Organic compounds that contain large proportions of nitrogen and oxygen tend to be unstable and are easily decomposed. Hexanitroethane, C2(NO2)6, decomposes according to the equation C2(NO2)6- 2NO, + 4NO + 2CO, The reaction in CCl, solvent is first order with respect to Cz{NO2)s At 63.7°C, k= 0.000254 s* and at 112.6°C, k = 0.0126s*. (a) What is the half-life of C2{NO2); at 63.7 °C? i seconds e Textbook and Media (b) What is the half-life of C2(NO2)s at 112.6 °C? seconds (c) IF0.100 mol of C2(NO2)6 is dissolved in CCI4 at 63.7°C to give 1.00 L of solution, what will be the C2(NO2), concentration after 50.0 minutes? i M (d) What is the value of the activation energy of this reaction, expressed in kilojoules? i kJ/mol (e) What is the rate constant at 159.4 °C?
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