In a cavity the total energ y U = aVT"i where d is îndependent of V and T. Show that F= + Tf (v) dnd S=4 d V TU-f(v) ,whece flu) Ps unknown. 3. Using g the fact that sao tor Ts o or as Ts o -> Show that the radiation pressure Ps. Pミu

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Chapter1: Chemical Foundations
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In a cavity the total energy
U = aVT4i where d is îndependent
of
T.
V and
Show that
F=
+ Tf(V)
dnd
S=4 d V TU-flv) ,wherce flu) Ps unknown.
Using the fact that s)o tor Ts o
or
as Tso
Show that the radiotion pressure P
P=
Transcribed Image Text:In a cavity the total energy U = aVT4i where d is îndependent of T. V and Show that F= + Tf(V) dnd S=4 d V TU-flv) ,wherce flu) Ps unknown. Using the fact that s)o tor Ts o or as Tso Show that the radiotion pressure P P=
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