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Give the synthesis pathway to synthesize the complex of trans-[PtCl2(en)(tu)] (structure below) by given the trans effect order is tu > Cl > en. Question: Does the answer below correct? Explain why. Which want we add first and replace first?

Give the synthesis pathway to synthesize the complex of trans-[PtCl2(en)(tu)] (structure below) by given the trans effect order is tu > Cl > en. Question: Does the answer below correct? Explain why. Which want we add first and replace first?

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Give the synthesis pathway to synthesize the complex of trans-[PtCl2(en)(tu)] (structure below) by given the trans effect order is tu > Cl > en.

Question: Does the answer below correct? Explain why.

  • Which want we add first and replace first?
Transeppecd : Irans effect of a spectator ligand or a group attached to metal canon is the tenden cy of that group to direct an InComing group to occupy the ept po siHon trans to it is called a Trans direeting group or trans director. This epfect is called Trans effect: To synthe size the complex of trans-[P+Cl2 Cen) (t Trans effect order : tu > CI> en - Syn theris af trans - [P+Cl2 cen) CH)] is carried out by thr treatment of CP+CI4]with Thioui ea. In the second 2 - Step, the Complex is treated with ethylene diamine. Since trans epfect of Thioureo is greoter than C, the incoming ethylenediamine ligand will occupy a positton trans to tliiourea. 2- tu - C1- t en CI H2 CI tu PI en CI
Transcribed Image Text:Transeppecd : Irans effect of a spectator ligand or a group attached to metal canon is the tenden cy of that group to direct an InComing group to occupy the ept po siHon trans to it is called a Trans direeting group or trans director. This epfect is called Trans effect: To synthe size the complex of trans-[P+Cl2 Cen) (t Trans effect order : tu > CI> en - Syn theris af trans - [P+Cl2 cen) CH)] is carried out by thr treatment of CP+CI4]with Thioui ea. In the second 2 - Step, the Complex is treated with ethylene diamine. Since trans epfect of Thioureo is greoter than C, the incoming ethylenediamine ligand will occupy a positton trans to tliiourea. 2- tu - C1- t en CI H2 CI tu PI en CI
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