Figure 19.36 This diagram shows the orientation of the tetrahedral ligands with respect to the axis system for the orbitals.

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CFT is applicable to molecules in geometries other than octahedral. In octahedral complexes, remember that the lobes of the eg set point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place,
but now we have only four ligands located between the axes (as given). None of the orbitals points directly at the tetrahedral ligands. However, the eg set (along the Cartesian axes) overlaps with the ligands less than does the t2g set. By analogy with the octahedral case, predict the energy diagram for the d orbitals in a tetrahedral crystal field. To avoid confusion, the octahedral eg set becomes a tetrahedral e set, and the octahedral t2g set becomes a t2 set.

Figure 19.36 This diagram shows the orientation of the tetrahedral ligands with respect to the axis system
for the orbitals.
Transcribed Image Text:Figure 19.36 This diagram shows the orientation of the tetrahedral ligands with respect to the axis system for the orbitals.
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