During the electrolysis of an aqueous KCI solution using inert electrodes, two of the following reactions take place at the electrodes, respectively. The pH of the solution around one or both of the electrodes changes as the reaction proceeds. (1) 2H,0() +2e-H,(g) +20H-(aq) (2) H,(g) +20H¯(aq) → 2H,0(€) +2e- (3) 0,(g) + 4H,0*(aq) +4e 6H,0() (4) 6H,0(6) →0,(g) +4H,0*(aq) + 4e - (5) 2Ce ( aq) → ce,(g) +2e- (6) Ce,(g) + 2e- → 20e-(aq) (type (type 'negative' or 'positive') electrode, at which The cathode is the 'reduction' or 'oxidation') takes place. As the reaction proceeds, the pH at this electrode or decreases'). (type 'increases' (choose from reactions (1) to (6) above - type your answer as a The reaction taking place at the anode is number within brackets, eg (3). (type 'out of or 'into') the electrode. Electron flow between the external circuit and the anode is

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Hint: In this question you must make use of your knowledge of thermodynamics and the redox potential table.
During the electrolysis of an aqueous KCI solution using inert electrodes, two of the following reactions take place at the electrodes,
respectively. The pH of the solution around one or both of the electrodes changes as the reaction proceeds.
(1) 2H,0(6) +2e--H,(g) +20H¯(aq)
(2) H,(g) +20H¯(aq) → 2H,0(6) + 2e-
(3) 0,(8) + 4H,0*(aq) + 4e¯ → 6H,0(6)
(4) 6H,0 (6) →0,(g) +4H,0*(aq) + 4e-
(5) 2Ce- ( aq) → Ce,(g) +2e¯
(6) Ce,(g) +2e¯ – 2C²¯ (aq)
(type 'negative' or 'positive') electrode, at which
(type
The cathode is the
"reduction' or 'oxidation') takes place. As the reaction proceeds, the pH at this electrode
or decreases').
(type 'increases'
(choose from reactions (1) to (6) above - type your answer as a
The reaction taking place at the anode is
number within brackets, eg (3)).
(type 'out of or 'into') the electrode.
Electron flow between the external circuit and the anode is
Transcribed Image Text:Hint: In this question you must make use of your knowledge of thermodynamics and the redox potential table. During the electrolysis of an aqueous KCI solution using inert electrodes, two of the following reactions take place at the electrodes, respectively. The pH of the solution around one or both of the electrodes changes as the reaction proceeds. (1) 2H,0(6) +2e--H,(g) +20H¯(aq) (2) H,(g) +20H¯(aq) → 2H,0(6) + 2e- (3) 0,(8) + 4H,0*(aq) + 4e¯ → 6H,0(6) (4) 6H,0 (6) →0,(g) +4H,0*(aq) + 4e- (5) 2Ce- ( aq) → Ce,(g) +2e¯ (6) Ce,(g) +2e¯ – 2C²¯ (aq) (type 'negative' or 'positive') electrode, at which (type The cathode is the "reduction' or 'oxidation') takes place. As the reaction proceeds, the pH at this electrode or decreases'). (type 'increases' (choose from reactions (1) to (6) above - type your answer as a The reaction taking place at the anode is number within brackets, eg (3)). (type 'out of or 'into') the electrode. Electron flow between the external circuit and the anode is
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