Answered: Draw the structure of…

Draw the structure of ethylenediaminetetraacetate ion (EDTA“) is reacted with Mn" forming an octahedral geometry. chelate when the polydentate ligand,

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds

Section: Chapter Questions

Problem 95QRT

See similar textbooks

Related questions

Q: The energies of the valence of orbitals on the iron atom in the octahedral [Fe(H₂O),] complex are…

A: Metals forming Coodination complexes have d electrons, and this splits according to the ligand…

Q: How is ligand bound to a protein? List the physical forces?

A: The forces through which one ion or molecule is bounded to another ion or molecule are termed as…

Q: For the coodination compound [CoCl(NO2)(NH3)4]Cl identify: A) the coordination number of the metal…

A: Given compound is [CoCl(NO2)(NH3)4]Cl we have to find : coordination number of metal oxidation…

Q: Which one of the following statements is FALSE? O In an octahedral crystal field, the d electrons on…

A: so we will determine the false statement of this question.

Q: Consider an octahedral complex where strong field ligands are bound to a central metal having a d…

Q: give an example of hexadentate ligand.

A: Ligands with six atoms with six lone pair of electrons that coordinates with metal atom are called…

Q: A given ligand is tetradentate. How many ligand donor atoms does it have? Enter your answer as a…

A: The objective of the question is to identify-The ligand donor atoms does tetradentate have.The…

Q: K2[Cu(CN)2Cl2] a.Systematic name b.The coordination number c.The correct hybridization for the…

Q: Based on the structures provided below, choose the incorrect statement. ethylene diamine (-) do op…

Q: The complex potassium dicyanoargenate(I) is used to make antiseptic compounds. Give the formula and…

Q: is nitric oxide (NO) an ambidentate ligand?

A: ✓ A ligand is an ion or molecule that binds to a central metal atom to form a coordination…

Q: Draw all possible resonance structures for each of the following ligands. Indicate the formal charge…

Q: CoCl3(H2N-CH2-CH2-NH2)2(H2O) corresponds to the empirical formula of two coordination compounds…

A: Coordination compounds are those in which a metal atom or ion forms coordinate bonds with the…

Q: Assume that there are 58.00 g of C2O4-2 and 12.27 g of iron in a 100 g sample of your unknown. What…

A: Mass of the whole sample is 100g. It contains oxalate, water and iron with it. The mass of iron and…

Q: CN- ion is a strong field ligand whereas Clis usually a weak field ligand. Draw d orbital energy…

Q: Consider the compound (C8H8)Ru(CO)3 which is likely to be the best description of the C8H8 ligand ?

A: The stability of any organometallic compound is given by Effective Atomic Number (EAN Rule).…

Q: Apply the concept of crystal-field theory to explain some of the interesting spectral and magnetic…

A: The Crystal Field Theory (CFT) is a theory for the bonding interaction between transition metals and…

Q: When we consider the reaction of Ag+ ion (SCN) with its ligand, by showing the ion-ligand bond in…

A: In this reaction two types of bonds can occur because the ligand SCN is an ambidentate ligand.…

Q: Both H2O and ethylenediamine (en) have two nonbonding pairs of electrons. Why can en act as a…

Q: Using crystal field theory, draw an electron box energy level diagram for the valence d orbitals on…

A: IntroductionCreate an energy level diagram for the valence d orbitals on the manganese atom in a…

Q: When we consider the reaction of Fe3+ ion (SCN) with its ligand, by showing the ion-ligand bond in…

A: The reaction between Fe3+ and SCN- could be given as, Fe3+aq+SCN-aq→FeSCN2+ SCN- is a thiocyanate…

Q: For the complex [RuCl2(2-phenylazopyridine)2], there are 5 possible geometric isomers. Please draw…

A: A question about coordination compounds, which is to be accomplished.

Q: Determine the charge of the metal center in diaquadibromoplatinum, [Pt(H2O)2Br2]. a.Draw the…

A: Geometrical isomers are the type of stereoisomers in which the species have same molecular formula…

Q: Chapter 19, Question 56 Cu forms tetrahedral complexes with some anionic ligands. When CuSO, SH₂O…

A: We are given blue vitrol ( CuSO4.5H2O) . We have to find out the balanced chemical reaction of…

Q: Draw d orbital energy diagrams for the following octahedral complexes and determine the number of…

Q: Write an equation for the reaction of a metal ion with a ligand in natural water (which functional…

A: EDTA is ethylenediaminetetraacetic acid is a ligand, also an indicator. It has 2 amino and 4…

Q: Does coordination of NO as a ligand to an electron-rich transition metal cause the N—O bond length…

A: NO is a strong pi acceptor ligand, so it can accept the electron from the metal d orbital.

Q: What is the oxidation number of the metal center? (please show the charges of the ligands).

Q: The oxidation state of the metal atom is metal atom is in the complex: and the coordination number…

A: Given complex: To determine:1) Oxidation state of metal atom2) Cordination number of metal atom

Q: Determine the oxidation state of the transition metal in each of these coordination compounds.…

A: The oxidation states of the ligands present in the coordination compounds:LigandOxidation…

Q: Compare the two complex ions formed with cobalt: 750 | 400 Red Violet 630 430 Co(H20)62* is ruby-red…

A: Co(H2O)62+ is ruby-red and Co(X)62+ is blue.

Q: The energies of the valence d orbitals on the manganese atom in the octahedral [MnF, complex are…

A: In an octahedral complex ion, d electrons are filled in the increasing order of energy of the d…

Q: Dimethyldithiocarbamate (abbreviated as dmdtc) is an anionic bidentate ligand with a chemical…

A: dmdtc is a bidentate strong field anionic ligand.

Q: 20) As the wavelength of the light observed (seen by the Eye) by the complex get longer: a) The…

A: Co-ordination compounds are formed when the metal ion is bonded to the ligand which donates its…

Q: Name the following metal complexes or complex ions: formula name [Fe(OH), (en); ] [v(eN), (NH,).]…

Q: Transition metal complexes containing CN ligands are often in yellow in color, whereas those…

A: The color of transition metal complexes is due to the absorption of specific wavelengths of visible…

Q: Uses crystal field theory (CCT) to predict the number of unpaired electrons in the following…

Q: The molecule CO is a common ligand in transition metal complexes forming a strong bond with the…

A: Carbon monoxide(CO) is a monobasic neutral ligand.

Q: K2[Cu(CN)2Cl2] a. Systematic name or formula b. The coordination number c. The possible geometry…

A: As per our guidelines, I can answer only first three sub-parts. Because you have posted multiple…

Q: A) Using a cobalt (III) ion as the central metal atom, and with chloride ions (Cl-) and ammonia…

Q: The energies of the valence d orbitals on the iron atom in the octahedral (Note: the d orbitals are…

A: Metals forming coordination complexes have d electrons, and this splits according to the ligand…

Q: Which of the following ligands is bidentate?

A: Edta , diene and triene have more than 2 donor sites.

Concept explainers

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.

Question

Draw the structure of
ethylenediaminetetraacetate ion (EDTA“) is reacted with Mn" forming an octahedral
geometry.
chelate when the polydentate ligand,

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

What is the coordination number of the central metal atom in the following complexes? (a) [Fe(H2O)63+] (b) [Pt(NH3)Br3] (c) [V(en)Cl42] (d) [Au(CN)2+]
Trimethylphosphine, P(CH3)3, can act as a ligand by donating the lone pair of electrons on the phosphorus atom. If trimethylphosphine is added to a solution of nickel(Il) chloride in acetone, a blue compound that has a molecular mass of approximately 270 g and contains 21.5% Ni, 26.0% Cl, and 52.5% P(CH3)3 can be isolated. This blue compound does not have any isomeric forms. What are the geometry and molecular formula of the blue compound?
Four different octahedral chromium coordination compounds exist that all have the same oxidation state for chromium and have H2O and Cl as the ligands and counterions. When 1 mole of each of the four compounds is dissolved in water, how many moles of silver chloride will precipitate upon addition of excess AgNO3?
The glycinate ion, H2NCH2CO2, formed by deprotonation of the amino acid glycine, can function as a bidentate ligand, coordinating to a metal through the nitrogen of the amino group and one of the oxygen atoms. Glycinate ion, a bidentate ligand A copper complex of this ligand has the formula Cu(H2NCH2CO2)2(H2O)2. For this complex, determine the following: (a) the oxidation state of copper (b) the coordination number of copper (c) the number of unpaired electrons (d) whether the complex is diamagnetic or paramagnetic
For each d electron configuration, state the number of unpaired electrons expected in octahedral complexes. Give an example complex for each case. (Two answers are possible for some of these cases.) (a) d2 (b) d4 (c) d6 (d) d8
Nickel and palladium both form complexes of the general formula M(PR3)2Cl2. (The ligand PR3 is a phosphine such as P(C6H5)3, triphenylphosphine. It is a Lewis base.) The nickel(II) compound is paramagnetic whereas the palladium(II) compound is diamagnetic. (a) Explain the magnetic properties of these compounds. (b) How many isomers of each compound are expected?
Sketch and explain the most likely crystal field diagram for the following complex ion: Note: The CN ligand produces a much stronger crystal field than NH3. Assume the NH3 ligands lie on the z axis.