Consider the following two ligand exchange reactions: [Co(H,0)6] + 6NH, = [Co(H,0) + 3en (Co(en),] + 6H,0 [Co(NH,) + 6H,0 (a) Which of the reactions should have a larger AS"? (b) Given that the Co-N bond strength is approxi- mately the same in both complexes, which reaction will have a larger equilibrium constant? Explain your choices.

Q: Name each of the compounds or ions given. (a) [Co(en)2(NO2)Cl]+(b) [Co(en)2Cl2]+(c) [Pt(NH3)2Cl4](d)…

A: Given compounds and ions    (a) [Co(en)2(NO2)Cl]+   (b) [Co(en)2Cl2]+   (c) [Pt(NH3)2Cl4]   (d)…

Q: Determine the oxidation state of metals and its electronic configuration for the following complexes…

A: To determine the oxidation state of metals and their electronic configurations in the given…

Q: 3. Assuming that each of the following compounds contains an octahedral complex ion, which compound…

A: (A) Co(NH3)Cl3

Q: Write

A: Dear student I have given answer to your question in the image format.

Q: 3. Amino acids can act as ligands toward transition metal ions. The simplest amino acid is glycin…

A:

Q: In acidic aqueous solution, the purple complex ion Co(NH3)5Br2+  undergoes a slow reaction in which…

A: Given,Initial concentration of Co(NH3)5 Br2+ = 0.100 Mrate constant = 6.3×10−6 s-1the molarity of…

Q: Cr(iii), Mn(ii), Fe(ii), Fe(iii), Co(ii), Ni(ii), Cu(ii), Zn(ii),  in solution reacts with NH4Cl .…

A: Different reactions can occur when Cr(III), Mn(II), Fe(II), Fe(III), Co(II), Ni(II), Cu(II), and Zn(…

Q: Give the number of d electrons (n of dn) for the central metal ion in (a) [Cr(H2O)6](ClO3)2; (b)…

A: Electronic configuration is used to describe how the electrons of an atom/ion are distributed in the…

Q: Give the proper name for each of the following compounds: (a) Pt(NH3)2Cl2 (b) [Rh(NH3)5Cl]Cl2 (c)…

A: since you have posted a question with multiple subparts, we are entitiled to answer answer only…

Q: 6a. Some ligands are multifunctional; that is, they have two or more atoms which can bind to the…

A:

Q: The complex diamminedichloroplatinum(II), [Pt(NH3)2CI2], is diamagnetic and exhibits geometrical…

A: If we check the oxidation state of Pt  Pt + 0 - 2 = 0 Pt = 2 NH3 being neutral molecule contributes…

Q: The spectrochemical series is I< Br¯< Cl <F< OH<H2O<NH3 < en< NO2 < CN Which of the following…

A: The complex having higher C.F.S.E. will absorb radiation of higher energy.

Q: 1. A complex is made up of one ammonia ligand, one cyanide ligand, two nitrite ligands bonded at the…

A: Explanation1.a)  Ligands present in the complex are NH3 (one), -CN- (one), -ONO- (two) Central metal…

Q: At 580 nm, the wavelength of maximum absorption, the complex Fe(SCN)2+ has a molar absorptivity of…

A:

Q: Determine the coordination number (c.n.) and the oxidation state (o.s.) of the transition metal in…

A: Since you have posted a question with multiple sub parts, we will solve first three sub parts for…

Q: (a) What is the crystal field splitting energy (Δ)?(b) How does it arise for an octahedral field of…

A: a) The crystal field splitting energy is the energy difference between the two sets of d orbitals…

Q: 8. The crystal field theory provides an explanation of color in various coordination complexes. For…

A:

Q: Q1. Answer all parts (a) – (d). (a) State the electronic configuration of a Co(ll) ion in the…

A: Answer

Q: Write out structure representations for all isomers of the following complexes: (a)…

A:

Q: Co(H2O)6]2+ (aq) + 4 Cl-(aq )⇆ [CoCl4]2-(aq) + 6 H2O    3. Does the value of the equilibrium…

A: Equilibrium constant is defined as the ratio of partial pressure of products to the partial pressure…

Q: Of the following complex ions, the one with probably the highest formation constant will be: (a)…

A: Given complexes,              a. [Co(en)3]3+(en represents ethylenediamine)              b.…

Q: The average human body contains 5.50 L of blood with a Fe²+ concentration of 3.20x10-5 M. If a…

A: We will use the balanced chemical equation of Fe2+ and CN- to solve this question. Fe2+ + 6CN-…

Q: Give the name of the following compounds according to the latest IUPAC nomenclature. (a)…

A: The IUPAC name of a coordination compounds follows the following rules: 1. A compound containing…

Q: Pyridine (CsHgN), abbreviated py, is the molecule N: (a) Would you expect pyridine to act as a…

A: Ligands Ligands in the coordinated complex is the ion or neutral molecule that act as the lewis base…

Q: 4. a) The molecule dimethylphophinoethane [(CH3)2PCH2CH2P(CH3)2]. which is abbreviated dmpe is used…

A: Part 1: The lewis structure of dmpe is as follows.

Q: Assign a following chemical compounds. Compound Name (a) Na[Mn(CN)5] fill in the blank 1 (b)…

A: Here we have to write systematic names of the following co-ordinate compounds.

Q: The octahedral complex ion [MNCI]³¯ has more unpaired spins than the octahedral complex ion…

A: In case of CFT, concept of strong ligand and weak ligand arises in case of pairing energy and…

Q: The equilibrium-constant expression for the reaction Ti (s) + 2CI 2 (g) TICI 4 () is given by O Ti…

A:

Q: Give the oxidation state of the metal species in the complex ion. [Fe(CN),(CO),P-

A: The complex given is Fe[(CN)4(CO)2]2–  The oxidation state of Fe = ?

Q: (i) Write the IUPAC name of the complex [Cr(NH3)4Cl2]Cl(ii) What type of isomerism is exhibited by…

A: NOTE ; Since you've posted multiple independent questions,we're solving only first question for you.…

Q: nich is the crystal field energy level diagram for a square pyramidal ML5 complex that contains a…

A:

Q: (i) What type of isomerism is shown by the complex [Cr(H2O)6]Cl3?(ii) On the basis of crystal field…

A: Since you have asked multiple question, we will solve the first question for you. If you want any…

Q: Which of the following is most paramagnetic? (a) Fe . (b) Fe3 + ion (c) The ion complex [Fe (CN) 6]…

A: Paramagnetic substances can be defined as the substances that contain unpaired electrons.

Q: a) (i) Draw the structure of [Co(CO)2(NO)(cot)] where cot is cyclooctatriene. (ii) What is the…

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Q: Sketch the following complexes. If more than one enantiomer exists, sketch just one. (a)…

A: Given -&gt; -&gt; In mer isomer three groups are on same plane , whereas in fac three similar groups…

Q: Write the hybridization, shape and magnetic character of [Fe(CN)6]4-.

A:

Q: (b) When NH3 is added to aqueous CuSO4, the complex [Cu(OH2)2(NH3)4]*+ is ultimately formed.…

A: When NH3 is added to aqueous CuSO4, the complex [Cu(OH)2(NH3 )4]2+ is ultimately formed. Initially,…

Q: a) Consider the following coordination compound [Fe(H₂O)2(en)2][SO4] and answer the questions which…

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Q: Use the thermodynamic data given below to compute the formation constant, Kf for [Zn(NH3)4]2+ in…

A: Answer:- Firstly a balanced equilibrium equation is written then using given standard enthalpy vqand…

Q: What are the charge and coordination number of the centralmetal ion(s) in each compound:(a)…

A: Coordination number It is the number of ligands attached to the metal center in a coordination…

Q: (4) Account for the relative rates of the following two reactions: [Fe(CN).J • [*Fe(CN).J*…

A:

Q: 4. Consider the following reaction: [ZnCl4] + 4 OH → [Zn(OH)4]² +4 CI If the reaction is…

A: The question is based on the concept of hard soft acid base (HSAB) principle.According to the…

Q: What is the charge on each of the following complex ions? hexaaquairon(II), [Fe(H2O)6]?…

A: 1.) Charge on hexaaquairon(II) Is +2   The oxidation state or charge on the central metal ion, Fe =…

Q: Which of the following order is true with respect to the color/electronic spectra of [Fe(H2O)6]3+,…

A: According to Lambert-Beer law, when light of intensity, Io passes through the solution, then the…

Q: (a) Give the chemical name of Ir(CO)CI(PPh3) 2 (either of the two isomers). (b) Sketch all isomers…

A: Coordination isomerism is a structural isomerism in which the composition of the coordination…

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.