Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(i) What are the thermodynamic quantities of a system that affect the amount and sign of
the internal energy change of a system? _________________________________
(ii) Consider the process represented by the following chemical equation:
NH4NO3
(s)
H2O(l)
NH4
+
(aq) + NO3
(aq) H = +28.05 kJ/mol
Using correct thermodynamic terminology, explain the sign of ΔTsurroundings for this
process.
(b) Study the following thermochemical data very carefully:
Cl2(g) → 2Cl(g) ΔH° = 242.3 kJ
I2(g) → 2I(g) ΔH° = 151.0 kJ
ICl(g) → I(g) + Cl(g) ΔH° = 211.3 kJ
I2(s) → I2(g) ΔH° = 62.8 kJ
I2(s) reacts with Cl2(g) to produce ICl(g).
Write the chemical equation to produce ONLY one mole of ICl(g)
___________________________________________
(i) Calculate ΔH° for the reaction of I2(s) with Cl2(g) to form 1 mole of ICl(g).
Use all the data given above

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