Below is a chromatogram observed from chemical separation of chlorinated pesticides using gas chromatography. Water samples were pre-treated using solvent extraction technique prior to injection into GC. Complete the statements below so that the sentences will be accurate and logical. Gas chromatography coupled with __________ __________ detector is suitable for chlorinated pesticide analysis. ii. Peaks that emerge first will represent compounds that are the most __________.Those compounds will also likely have low boiling points and show the least interactions with the stationary phase. iii. Major peaks start to emerge after 24 minutes. Heating the GC oven containing the column will likely __________ the time of chromatographic separation. iv. The peak height or area of an analyte is used to determine its __________ in quantitative analysis.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Below is a chromatogram observed from chemical separation of chlorinated pesticides using gas chromatography. Water samples were pre-treated using solvent extraction technique prior to injection into GC. Complete the statements below so that the sentences will be accurate and logical.

Gas chromatography coupled with __________ __________ detector is suitable
for chlorinated pesticide analysis.


ii. Peaks that emerge first will represent compounds that are the most __________.Those compounds will also likely have low boiling points and show the least
interactions with the stationary phase.


iii. Major peaks start to emerge after 24 minutes. Heating the GC oven containing the column will likely __________ the time of chromatographic separation.


iv. The peak height or area of an analyte is used to determine its __________ in quantitative analysis.

Chlorinated pesticides in water
1. Propachlor
2. Trifluralin
13. a-Chlordane
14. Dieldrin
3. a-HCH
15. p.p-DDE
4. Hexachlorobenzene 16. Endrin
5. B-HCH
6. y-HCH
7. SHCH
8. Heptachlor
9. Aldrin
10. DCPA
11. Heptachlor Epoxide 23. trans-Permethrin
12. z-Chlordane
17. p.p'DDD
18. Endrin Aldehyde
19. Endosulfan Sulfate
12 14
-15
11 13 16
20. p.p'DDT
21. Methoxychlor
22. cis-Permethrin
21
2
10
20
17
23
|18
19
22
12
16
20
24
28
32
36 40
44
48
52 Min.
Transcribed Image Text:Chlorinated pesticides in water 1. Propachlor 2. Trifluralin 13. a-Chlordane 14. Dieldrin 3. a-HCH 15. p.p-DDE 4. Hexachlorobenzene 16. Endrin 5. B-HCH 6. y-HCH 7. SHCH 8. Heptachlor 9. Aldrin 10. DCPA 11. Heptachlor Epoxide 23. trans-Permethrin 12. z-Chlordane 17. p.p'DDD 18. Endrin Aldehyde 19. Endosulfan Sulfate 12 14 -15 11 13 16 20. p.p'DDT 21. Methoxychlor 22. cis-Permethrin 21 2 10 20 17 23 |18 19 22 12 16 20 24 28 32 36 40 44 48 52 Min.
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