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b) 0 th, pd/c HNO3 1504 0 NO₂ 0 میل الدین سہتی ہو 400 NaNO₂, HCl " NO₂ 34 product Short syntheses for both compounds are given in image.

b) 0 th, pd/c HNO3 1504 0 NO₂ 0 میل الدین سہتی ہو 400 NaNO₂, HCl " NO₂ 34 product Short syntheses for both compounds are given in image.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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-CH₂ HNO3 1504 1/₂, pd/c NO₂ 0 ದ 0 olyan NaNO₂, HCl Cuc FO НО HC CH₂ ANO₂ 0 product Short syntheses for both compounds are given in image. a)Nitration of the aromatic ring followed by acid catalysed reduction gives amine. Then Sandmeyer reaction for yielding diazonium salt followed by reaction with Cul gives iodo compound. Pd catalysed Heck coupling of this iodo compound with styrene will give the desired product. b)o-nitration of toluene followed by Friedel crafts acylation (using AICI3) for introducing carbonyl group. Selective reduction of Nitro using Hydrogen and Pd on C will give amine. This amine will undergo Sandmeyer reaction forming diazonium salt and then using CuCl, chloro will be placed hence giving required product.
Transcribed Image Text:-CH₂ HNO3 1504 1/₂, pd/c NO₂ 0 ದ 0 olyan NaNO₂, HCl Cuc FO НО HC CH₂ ANO₂ 0 product Short syntheses for both compounds are given in image. a)Nitration of the aromatic ring followed by acid catalysed reduction gives amine. Then Sandmeyer reaction for yielding diazonium salt followed by reaction with Cul gives iodo compound. Pd catalysed Heck coupling of this iodo compound with styrene will give the desired product. b)o-nitration of toluene followed by Friedel crafts acylation (using AICI3) for introducing carbonyl group. Selective reduction of Nitro using Hydrogen and Pd on C will give amine. This amine will undergo Sandmeyer reaction forming diazonium salt and then using CuCl, chloro will be placed hence giving required product.
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