4. A 50.0 g sample of argon (39.95 g/mol) is placed in a container of 0.925L at 325K. a. Calculate P using the Ideal gas EOS. b. Calculate P using the van der Waals EOS. (a=1.355 12 bar/mol2, b=0.0320 L/mol) c. Are the attractive or repulsion contributions dominant in this system? d. Will the Z value for this system be greater than, less than or equal to one? e. What does this mean for the amount of work needed to compress this system versus an ideal gas system under the same conditions?
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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