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Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please explain question 15 and draw out the mechanism using the correct reagent. Explain the other reagents if possible 

3:28
• N © ✨ <ll 74% ■
O
14) Select the best set of reagents to accomplish the following transformation.
HO
a) i) LiAlH4; ii) H₂O
c) i) DIBALH, -78°C; ii) H₂O
b) i) NaBH4; ii) H₂O
d) H2(g), Raney Ni
15) Select the major product of the following reaction.
HO
H3O+, heat
?
OH
c)
OH
OH
HO
OH
H
HO
16) Select the major product of the following reaction.
NH₂
SOCI₂, heat
?
b)
OH
NH₂
17) A compound with the molecular formula CsH10O2 is reported to smell like pineapple. The
'H NMR of the compound is shown below. What is the name of the compound?
2H,
quartet
3H, 3H,
triplet triplet
2H,
quartet
a) methyl butanoate
b) ethyl propanoate
c) pentanoic acid
d) propyl ethanoate
ppm
Page 4 of 8
<
Transcribed Image Text:3:28 • N © ✨ <ll 74% ■ O 14) Select the best set of reagents to accomplish the following transformation. HO a) i) LiAlH4; ii) H₂O c) i) DIBALH, -78°C; ii) H₂O b) i) NaBH4; ii) H₂O d) H2(g), Raney Ni 15) Select the major product of the following reaction. HO H3O+, heat ? OH c) OH OH HO OH H HO 16) Select the major product of the following reaction. NH₂ SOCI₂, heat ? b) OH NH₂ 17) A compound with the molecular formula CsH10O2 is reported to smell like pineapple. The 'H NMR of the compound is shown below. What is the name of the compound? 2H, quartet 3H, 3H, triplet triplet 2H, quartet a) methyl butanoate b) ethyl propanoate c) pentanoic acid d) propyl ethanoate ppm Page 4 of 8 <
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