24.3 Ethyl-ether is produced by the dehydration of ethanol over a suitable catalyst 2C2H5OH → (C2H5)2O + H2O The feed to the process (F) is industrial ethanol containing 12 % water and 3 % methanol (CH3OH). It is mixed with a recycle stream (R) and charged to the reactor. The methanol content of the reactor feed stream (A) must be limited to 9.8 %. The reactor product stream is passed through two separators. In the first separator all the ethyl-ether is recovered as pure ethyl-ether (E). In the second separator a part of the water is recovered as pure water (W). The second separator also yields the recycle stream, consisting of a mixture of ethanol, methanol and water containing 70 % ethanol and 15 % methanol. To limit the methanol content in the feed to the reactor, part of this stream is purged (P). A schematic representation of the process is shown.

Introduction to Chemical Engineering Thermodynamics
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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24.3 Ethyl-ether is produced by the dehydration of ethanol over a suitable catalyst
2C2H5OH → (C2H5)2O + H2O
The feed to the process (F) is industrial ethanol containing 12 % water and 3 %
methanol (CH3OH). It is mixed with a recycle stream (R) and charged to the reactor.
The methanol content of the reactor feed stream (A) must be limited to 9.8 %. The
reactor product stream is passed through two separators. In the first separator all the
ethyl-ether is recovered as pure ethyl-ether (E). In the second separator a part of the
water is recovered as pure water (W). The second separator also yields the recycle
stream, consisting of a mixture of ethanol, methanol and water containing 70 % ethanol
and 15 % methanol. To limit the methanol content in the feed to the reactor,
stream is purged (P). A schematic representation of the process is shown.
part of this
R
P
F
A
Mixer
Reactor
Separator
Separator
E
W
The fresh feed (F) to the process is 100 kg/h.
Calculate the following:
(a) The purge rate (P) in kg/h
(b) The production rate of the ether (E) in kg/h
(c) The conversion in the reactor
(d) The conversion in the process
Transcribed Image Text:24.3 Ethyl-ether is produced by the dehydration of ethanol over a suitable catalyst 2C2H5OH → (C2H5)2O + H2O The feed to the process (F) is industrial ethanol containing 12 % water and 3 % methanol (CH3OH). It is mixed with a recycle stream (R) and charged to the reactor. The methanol content of the reactor feed stream (A) must be limited to 9.8 %. The reactor product stream is passed through two separators. In the first separator all the ethyl-ether is recovered as pure ethyl-ether (E). In the second separator a part of the water is recovered as pure water (W). The second separator also yields the recycle stream, consisting of a mixture of ethanol, methanol and water containing 70 % ethanol and 15 % methanol. To limit the methanol content in the feed to the reactor, stream is purged (P). A schematic representation of the process is shown. part of this R P F A Mixer Reactor Separator Separator E W The fresh feed (F) to the process is 100 kg/h. Calculate the following: (a) The purge rate (P) in kg/h (b) The production rate of the ether (E) in kg/h (c) The conversion in the reactor (d) The conversion in the process
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