2. Synthesize the target compounds (C1-5) by matching the following starting materials with the appropriate reagents. B1. LIAIH4 C1. PHCH=CHCOCH3 A1. PHCOCH3 B2. Zn.Hg / HCI C2. PHCH2OH+ PHCOOH A2. PHCHO B3. CH3COCH3/NaOH C3. PHCOOC2H5 B4. C2H5OH / H2SO4 C4. PHCH(OH)CH3 A3. PHCOOH B5. KOH C5. PHCH3
Reactions of Ethers
Ethers (R-O-R’) are compounds formed by replacing hydrogen atoms of an alcohol (R-OH compound) or a phenol (C6H5OH) by an aryl/ acyl group (functional group after removing single hydrogen from an aromatic ring). In this section, reaction, preparation and behavior of ethers are discussed in the context of organic chemistry.
Epoxides
Epoxides are a special class of cyclic ethers which are an important functional group in organic chemistry and generate reactive centers due to their unusual high reactivity. Due to their high reactivity, epoxides are considered to be toxic and mutagenic.
Williamson Ether Synthesis
An organic reaction in which an organohalide and a deprotonated alcohol forms ether is known as Williamson ether synthesis. Alexander Williamson developed the Williamson ether synthesis in 1850. The formation of ether in this synthesis is an SN2 reaction.
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