2) The first law states that the energy of the universe is a constant (AU = q + w) while thesecond law states that the entropy of the universe tends always towards a maximum (AStot =AS + ASsurr 20). Answer the following questions only based on the conditions it is provided.(a) Assuming that the entropy change of the system is AS = qrey/T ,determine the relationshipof Asşurr in terms of qrev and T.(b) If only PV-work is considered, prove that the inequality of work (dwrev< dwir) is alwaysvalid (e.g., expansion or compression).(c) Prove dgrev> dqirr based on dwrev < dwir.(d) Based on dqrev > dqir to prove the Clausius inequality, dS > qrev/T , where the equalityholds only for reversible processes.(e) Following (c) and (d) to prove that the entropy change of any irreversible process isalways greater than zero in an isolated system.(f) Assuming that the system is no longer isolated, i.e., the surroundings are a reservoir ofenergy and the heat entering the system is equal to the heat leaving the surroundings. Showthat the Clausius inequality can be deduced to a more general expression for the 2nd law, i.e.,dS = dS + dSgurr 20'tot

Answered: Image /qna-images/answer/66b506b3-eaa0-4cf7-b5ff-0c38708784cf.jpg

2) The first law states that the energy of the universe is a constant (AU = q + w) while the second law states that the entropy of the universe tends always towards a maximum (AStot = AS + ASurr 20). Answer the following questions only based on the conditions it is provided. (a) Assuming that the entropy change of the system is AS = qrey/T ,determine the relationship of Assurr in terms of qrev and T. (b) If only PV-work is considered, prove that the inequality of work (dwrev< dwir) is always valid (e.g., expansion or compression). (c) Prove dqrev> dqirr based on dwrev< dwirr.

2) The first law states that the energy of the universe is a constant (AU = q + w) while the second law states that the entropy of the universe tends always towards a maximum (AStot = AS + ASurr 20). Answer the following questions only based on the conditions it is provided. (a) Assuming that the entropy change of the system is AS = qrey/T ,determine the relationship of Assurr in terms of qrev and T. (b) If only PV-work is considered, prove that the inequality of work (dwrev< dwir) is always valid (e.g., expansion or compression). (c) Prove dqrev> dqirr based on dwrev< dwirr.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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