CH 237 Experiment 4?

10) Synthesis: Make the following products from a suitable cyclic alkene starting material. Look at the functional group PATTERN present in the molecule, including stereochemistry. Br CH3 Br CH3

What is the mechanism for the hydraction of cyclohexene by oxymercuration?

From the table of available reagents select the one(s) you would use to convert:3-pentanol to 3-bromopentane:cyclopentanol to trans-2-methylcyclopentanol:Use the minimum number of steps; in no case are more than four steps necessary.List reagents by letter in the order that they are used; example: fa.

Select the reagent that you would use to convert an alkene to a Markovnikov (more substituted) alcohol without possibility of carbocation rearrangement. o H2SO4, H2O OBH3-THF, then H2O2, H2O, NaOH Hg(OAc)2, H2O, then NaBH4 o OsO4, TBHP, H2O

10. Terpene is a class of naturally occurring molecules, found in many essential oils from plants, that share the same alkene features. All terpenes have a similar 5 carbon unit that includes an alkene thought to be biologically synthesized from the molecule isoprene. All terpenes are biosynthesized from molecules with the good leaving group: pyrophosphate (OPP). Loss of this OPP leads to the formation of a resonance stabilized carbocation. The new carbocation can undergo a nucleophilic attack from a T-bond as seen in acid-catalyzed hydration and hydrohalogenation, forming a new carbocation. This new carbocation can undergo an E1 reaction to form a new alkene. Add the curved arrows of the following reaction. hopp COPP D 5 R-carvone (spearmint oil) - Q Search 40 6 & COPP 1 COPP COPP

help with these orgo chem questions

3 9 $ 4 R H₂C B % 5 1. Aqueous ethanol HBr CH₁ 2. OH a Proton transfer d E1 Elimination. f = SN1 Nucleophilic substitution b Lewis acid/base. e E2 Elimination g= SN2 Nucleophilic substitution c = Electrophilic addition The rections above involve synthesis or reactions of alcohols and ethers. Identify the mechanism by which they proceed from among the mechanisms listed. Use the letters a- g for your answers. 1. 2. Submit Answer Retry Entire Group 9 more group attempts remaining Previous Next> Save and Exit Cengage Learning Cengage Technical Support O 8:15 AM 6/20/2022 PrtScn PgDn F5 F6 T B CH₂ Nà Nha ^ 6 Y H N & 7 [Review Topics] H₂C U 8 M CH₂ NH₂ K [References] H₂C 73°F Sunny Home ( 9 O L End 0 G F10 P PgUp 4x F12 □

+ 5 Predict the major products of both organic reactions. Be sure to use wedge and dash bonds to show the stereochemistry of the products when it's important, for example to distinguish between two different major products. : ☐ 円 H₂O Click and drag to start drawing a structure. H2SO4 ☐ : ☐ + х G 0 H2SO4, H₂O HgSO 4 Click and drag to start drawing a structure.

The compound below is treated with chlorine in the presence of light. H3C CH3 H3C° `CH2CH3 Draw the structure for the organic radical species produced by reaction of the compound with a chlorine atom. Assume reaction occurs at the weakest C-H bond. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms.

please draw the major products for both reactions

Draw the line-angle formula of the enol formed in the following alkyne hydration reaction and then draw the structural formula of the carbonyl compound with which this enol is in equilibrium. -C=CH 1. (sia)2BH 2. NaOH/H₂O₂ an enol carbonyl compound • You do not have to consider stereochemistry. • Draw both the enol and the carbonyl forms. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate structures using the sign from the drop-down menu. ChemDoodleⓇ <

The compound below is treated with chlorine in the presence of light. CH3 CH3 CH3 Draw the structure for the organic radical species produced by reaction of the compound with a chlorine atom. Assume reaction occurs at the weakest C-H bond. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. Sn [F ?

Draw a structural formula of an alkene or alkenes (if more than one) that undergo acid-catalyzed hydration and without rearrangement give 1-methylcyclohexanol as the major product. You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. ● If more than one structure fits the description, draw them all. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate structures with + signs from the drop-down menu. ● ● ✓ ? ChemDoodleⓇ n [ ]#

9.

help me please Please fill in the reagents,intermediates, and/or products of the following reactions.     all the reactions shall be covered in Chapter 12-15 from Organic Chemistry, 6th Edition by Marc Loudon and Jim Parise.

Questão 10A certain hydrocarbon had the molecular formula C16H26 and contained two triple bonds. Ozonolysis resulted in CH3(CH2)4CO2H and HO2CCH2CH2CO2H as the only products. What is the reasonable structure for this hydrocarbon? Hexadec-6,10-dino undec-1,5-dino Hept-1,5-dino hex-1,5-dino nah

Zaitsev's rule can be used to predict the major alkene product in a dehydration reaction. What is the name of the major product of the dehydration reaction shown below? CH3 CH3CHCH₂CHCH3 ОН 4-methyl-1-pentanol 4-methyl-4-pentene O2-methyl-2-pentanol 4-methyl-2-pentene H heat

An alkene having the molecular formula C5H10 is treated sequentially with ozone (O3) and zinc/acetic acid to give the product/s shown. H3C O CH3CHCH + H. Draw a structural formula for the alkene. You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. In cases where there is more than one answer, just draw one. P opy aste [* Previous Next

$ [References] H₂O + CO₂ + Nal CH₂ HỌC CHO a = Proton transfer d E1 Elimination - f SN1 Nucleophilic substitution = b = Lewis acid/base e E2 Elimination g = SN2 Nucleophilic substitution c = Electrophilic addition The rections above involve synthesis or reactions of alcohols and ethers. Identify the mechanism by which they proceed from among the mechanisms listed. Use the letters a - g for your answers. 1. 2. Submit Answer Retry Entire Group 9 more group attempts remaining Previous Next> Save and Exit Cengage Learning Cengage Technical Support PrtScn F6 F7 1. 2. O F4 % 5 T OH you. ♫ F5 ^ 6 Y H 1₂ H₂O NaHCO3 & 7 [Review Topics] into * 8 CH₂ H₂CH₂ CH₂ I F8 K + 73°F Sunny Home 9 O F9 L ) End 0 8:14 AM □ 6/20/2022 PgDn E = P P B F10 PgUp 4x F11 F12 Ins

Draw structural formulas for major organic product of the reaction shown below.

Predict the major products of this organic reaction. Be sure you use wedge and dash bonds when necessary, for example to distinguish between major products with different stereochemistry. : ☐ + Х RCO₂H 3 Click and drag to start drawing a structure.

A synthon is a concept in retrosynthetic analysis. It is defined as a structural unit within a molecule which is related to a possible synthetic operation. Example: OH bond breaks here synthesis Br + retrosynthesis NEC Na -NaBr Synthons C-C bond formation synthetic equivalents Br D=00 CN OH || ⒸC=N H₂O, H+ hydrolysis do not exist exist functional group transformation Common synthons: C1 synthons: carbon dioxide, carbon monoxide, cyanide, formaldehyde C2 synthons: acetylene, acetaldehyde C₂H4OH synthon: ethylene oxide OH Carbocation synthons: alkyl halides, carbonyl C Carbanion synthons: Grignard reagents, organolithiums, malonic ester/acetoacetic ester, terminal alkyne Use the synthons listed above, propose how you would synthesis the following molecules:

Describe how 1-ethylcyclohexanol can be prepared from cyclohexane. You can use any inorganic reagents, any solvents, and any organic reagents as long as they contain no more than two carbons.

The nitro groups on the benzene ring in the reactant serve two purposes.One is to let you know what atoms in the reactant correspond to what atomsin the product. But what role do the nitro groups play electronically – whywould the reaction be much slower if these nitro groups weren’t attached tothose benzene carbons? Draw any relevant structures to support youranswer.