Chapter 15 - Aqueous Ionic Equilibrium

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10/13/22, 2:00 AM Chapter 15 - Aqueous Ionic Equilibrium: General Chemistry: 2022FA-CHEM-001B-202 https://sjeccd.instructure.com/courses/32359/quizzes/198733 1/13 Chapter 15 - Aqueous Ionic Equilibrium Due Oct 23 at 11:59pm Points 22 Questions 22 Available Aug 29 at 12am - Dec 4 at 11:59pm Time Limit None Allowed Attempts 2 Instructions Attempt History Attempt Time Score KEPT Attempt 2 9 minutes 22 out of 22 LATEST Attempt 2 9 minutes 22 out of 22 Attempt 1 433 minutes 20 out of 22 Correct answers are hidden. Instructions: 1. You have two attempts for this assignment. Canvas will keep the highest score. 2. You should take screenshots of all the questions (and answers) after each attempt. You are only allowed to see the questions and answers ONCE (after each attempt). 3. You are only allowed to see your score ONCE after each attempt. You cannot see the answers to questions that are marked incorrectly. You can only see which questions are marked wrong. 4. This assignment may contain some embedded images. If you cannot see the images. it is most likely because you are using an Apple, Mac, or iPad. Canvas is designed to be compatible with Google Chrome. Do not use Safari. If you have an Apple, Mac, or iPad, try installing Google Chrome and using that browser (not Safari). Also. try moving your mouse cursor over the "missing" images. Then, "right click" with your mouse. Then, select "View", "Download", or "Save As". Many students said that would work. 5. If the due date has already past for this assignment, you are still allowed to go ahead and do the assignment. Just know that you are allowed to be late for only TWO Homework assignments for the entire semester. So, you can submit TWO late Homework assignments without any late penalty. After TWO late homework assignments, all other late Homework assignments will receive a ZERO. The very last date to submit late Homework assignments (up to two late assignments only) is December 4, 2022 (11:59 PM).
10/13/22, 2:00 AM Chapter 15 - Aqueous Ionic Equilibrium: General Chemistry: 2022FA-CHEM-001B-202 https://sjeccd.instructure.com/courses/32359/quizzes/198733 2/13 Score for this attempt: 22 out of 22 Submitted Oct 13 at 2am This attempt took 9 minutes. 1 / 1 pts Question 1 An important buffer in the blood is a mixture of ________. carbonic acid and bicarbonate ion acetic acid and bicarbonate ion acetic acid and carbonate ion sodium chloride and hydrochloric acid hydrochloric acid and sodium hydroxide 1 / 1 pts Question 2 Identify a good buffer. significant amounts of both a weak acid and a strong acid significant amounts of both a weak acid and its conjugate base small amounts of both a weak acid and its conjugate base significant amounts of both a strong acid and a strong base small amounts of both a strong acid and a strong base
10/13/22, 2:00 AM Chapter 15 - Aqueous Ionic Equilibrium: General Chemistry: 2022FA-CHEM-001B-202 https://sjeccd.instructure.com/courses/32359/quizzes/198733 3/13 1 / 1 pts Question 3 If the pKa of HCHO is 3.74 and the pH of an HCHO /NaCHO solution is 3.11, which of the following is TRUE? 2 2 2 [HCHO ] = [NaCHO ] 2 2 [HCHO ] < [NaCHO ] 2 2 [HCHO ] << [NaCHO ] 2 2 It is not possible to make a buffer of this pH from HCHO and NaCHO . 2 2 [HCHO ] > [NaCHO ] 2 2 1 / 1 pts Question 4 Calculate the pH of a buffer that is 0.225 M HC H O and 0.162 M KC H O . The K for HC H O is 1.8 × 10 . 2 3 2 2 3 2 a 2 3 2 -5 4.89 9.11 4.74 4.60 9.26 1 / 1 pts Question 5
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10/13/22, 2:00 AM Chapter 15 - Aqueous Ionic Equilibrium: General Chemistry: 2022FA-CHEM-001B-202 https://sjeccd.instructure.com/courses/32359/quizzes/198733 4/13 Calculate the pH of a solution formed by mixing 250.0 mL of 0.15 M NH Cl with 200.0 mL of 0.12 M NH . The K for NH is 1.8 × 10 . 4 3 b 3 -5 9.26 4.55 4.74 9.06 9.45 1 / 1 pts Question 6 Calculate the pH of a solution formed by mixing 200.0 mL of 0.30 M HClO with 300.0 mL of 0.20 M KClO. The K for HClO is 2.9 × 10 . a -8 7.06 8.01 6.46 7.54 5.99 1 / 1 pts Question 7 A 1.00 L buffer solution is 0.250 M in HF and 0.250 M in NaF. Calculate the pH of the solution after the addition of 100.0 mL of 1.00 M HCl. The K a
10/13/22, 2:00 AM Chapter 15 - Aqueous Ionic Equilibrium: General Chemistry: 2022FA-CHEM-001B-202 https://sjeccd.instructure.com/courses/32359/quizzes/198733 5/13 for HF is 3.5 × 10 . -4 3.09 3.46 2.78 3.82 4.11 1 / 1 pts Question 8 A 1.00 L buffer solution is 0.250 M in HF and 0.250 M in LiF. Calculate the pH of the solution after the addition of 0.150 moles of solid LiOH. Assume no volume change upon the addition of base. The K for HF is 3.5 × 10 . a -4 3.46 2.85 3.63 4.06 4.24 1 / 1 pts Question 9 Define buffer capacity.
10/13/22, 2:00 AM Chapter 15 - Aqueous Ionic Equilibrium: General Chemistry: 2022FA-CHEM-001B-202 https://sjeccd.instructure.com/courses/32359/quizzes/198733 6/13 Buffer capacity is the amount of acid or base that can be added to a buffer without destroying its effectiveness. Buffer capacity is the amount of base that can be added until all of the acid is used up. Buffer capacity is the amount of acid that can be added until all of the acid is used up. Buffer capacity is the amount of acid that can be added until all of the base is used up. Buffer capacity is the amount of base that can be added until all of the base is used up. 1 / 1 pts Question 10 When titrating a strong monoprotic acid and KOH at 25°C, the pH will be equal to 7 at the equivalence point. titration will require more moles of acid than base to reach the equivalence point. pH will be greater than 7 at the equivalence point. pH will be less than 7 at the equivalence point.
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10/13/22, 2:00 AM Chapter 15 - Aqueous Ionic Equilibrium: General Chemistry: 2022FA-CHEM-001B-202 https://sjeccd.instructure.com/courses/32359/quizzes/198733 7/13 titration will require more moles of base than acid to reach the equivalence point. 1 / 1 pts Question 11 When titrating a weak monoprotic acid with NaOH at 25°C, the pH will be greater than 7 at the equivalence point. titration will require more moles of acid than base to reach the equivalence point. titration will require more moles of base than acid to reach the equivalence point. pH will be less than 7 at the equivalence point. pH will be equal to 7 at the equivalence point. 1 / 1 pts Question 12 A 100.0 mL sample of 0.18 M HClO is titrated with 0.27 M LiOH. Determine the pH of the solution before the addition of any LiOH. 4 1.05 1.57
10/13/22, 2:00 AM Chapter 15 - Aqueous Ionic Equilibrium: General Chemistry: 2022FA-CHEM-001B-202 https://sjeccd.instructure.com/courses/32359/quizzes/198733 8/13 1.74 0.74 0.57 1 / 1 pts Question 13 A 100.0 mL sample of 0.18 M HClO is titrated with 0.27 M LiOH. Determine the pH of the solution after the addition of 30.0 mL of LiOH. 4 2.00 1.21 1.12 2.86 0.86 1 / 1 pts Question 14 A 100.0 mL sample of 0.10 M NH is titrated with 0.10 M HNO . Determine the pH of the solution after the addition of 50.0 mL of HNO . The K of NH is 1.8 × 10 . 3 3 3 b 3 -5 10.34 4.74 9.26
10/13/22, 2:00 AM Chapter 15 - Aqueous Ionic Equilibrium: General Chemistry: 2022FA-CHEM-001B-202 https://sjeccd.instructure.com/courses/32359/quizzes/198733 9/13 7.05 7.78 1 / 1 pts Question 15 Determine the molar solubility of AgBr in a solution containing 0.150 M NaBr. K (AgBr) = 7.7 × 10 . sp -13 0.150 M 8.8 × 10 M -7 5.8 × 10 M -5 3.9 × 10 M -13 5.1 × 10 M -12 1 / 1 pts Question 16 The molar solubility of ZnS is 1.6 × 10 M in pure water. Calculate the K for ZnS. -12 sp 1.6 × 10 -35 8.0 × 10 -13 3.2 × 10 -12 6.80 × 10 -5
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10/13/22, 2:00 AM Chapter 15 - Aqueous Ionic Equilibrium: General Chemistry: 2022FA-CHEM-001B-202 https://sjeccd.instructure.com/courses/32359/quizzes/198733 10/13 2.6 × 10 -24 1 / 1 pts Question 17 The molar solubility of Ag S is 1.26 × 10 M in pure water. Calculate the K for Ag S. 2 -16 sp 2 1.12 × 10 -8 1.59 × 10 -32 8.00 × 10 -48 6.81 × 10 -63 3.78 × 10 -12 1 / 1 pts Question 18 Give the equation for an unsaturated solution in comparing Q with K . sp Q = K sp Q K sp none of the above Q < K sp Q > K sp
10/13/22, 2:00 AM Chapter 15 - Aqueous Ionic Equilibrium: General Chemistry: 2022FA-CHEM-001B-202 https://sjeccd.instructure.com/courses/32359/quizzes/198733 11/13 1 / 1 pts Question 19 A solution containing AgNO is mixed with a solution of NaCl to form a solution that is 0.10 M in AgNO and 0.075 M in NaCl. What will happen once these solutions are mixed? K (AgCl) = 1.77 × 10 . 3 3 sp -10 Nothing will happen since the molar solubility of AgCl is higher than the solution concentrations. There is not enough information to say anything about this solution. Silver chloride will precipitate out of solution, leaving an unsaturated solution of AgCl. Nothing will happen since NaCl and AgNO are both soluble compounds. 3 Silver chloride will precipitate out of solution, leaving a saturated AgCl solution. 1 / 1 pts Question 20 A solution containing CaCl is mixed with a solution of Li C O to form a solution that is 3.5 × 10 M in calcium ion and 2.33 × 10 M in oxalate ion. What will happen once these solutions are mixed? K (CaC O ) = 2.3 × 10 . 2 2 2 4 -4 -4 sp 2 4 -9 There is not enough information to determine. A precipitate will form since Q > K for calcium oxalate. sp
10/13/22, 2:00 AM Chapter 15 - Aqueous Ionic Equilibrium: General Chemistry: 2022FA-CHEM-001B-202 https://sjeccd.instructure.com/courses/32359/quizzes/198733 12/13 A precipitate will form as calcium oxalate is not soluble to any extent. Nothing will happen since both calcium chloride and lithium oxalate are soluble compounds. Nothing will happen K > Q for all possible precipitants. sp 1 / 1 pts Question 21 A solution contains 0.021 M Cl and 0.017 M I . A solution containing copper (I) ions is added to selectively precipitate one of the ions. At what concentration of copper (I) ion will a precipitate begin to form? What is the identity of the precipitate? K (CuCl) = 1.0 × 10 , K (CuI) = 5.1 × 10 . sp -6 sp -12 4.8 × 10 M, CuCl -5 No precipitate will form at any concentration of copper (I). 4.8 × 10 M, CuI -5 3.0 × 10 M, CuCl -10 3.0 × 10 M, CuI -10 1 / 1 pts Question 22 A solution contains 2.2 × 10 M in Cu and 0.33 M in LiCN. If the K for Cu(CN) is 1.0 × 10 , how much copper ion remains at equilibrium? -3 2+ f 4 2- 25 2.9 × 10 M -27
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10/13/22, 2:00 AM Chapter 15 - Aqueous Ionic Equilibrium: General Chemistry: 2022FA-CHEM-001B-202 https://sjeccd.instructure.com/courses/32359/quizzes/198733 13/13 6.7 × 10 M -28 1.9 x 10 M -26 3.8 × 10 M -24 4.6 × 10 M -25 Quiz Score: 22 out of 22