SN2 post lab

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Which is the least reactive compound by the SN2 mechanism? Br I CH3CH₂CHCH3 O b.CH3CH₂CH₂CH₂Br a. O c. Br CH3CH₂C(CH3)2 O d. (CH3)2CHCH₂Br

This reaction does not follow the expected theory. Given what you know about substitution/elimination, what is the expected mechanism this reaction should follow? Suggest why that is not what happens and give the actual product of the reaction. Br ткон s

help please answer in text form with proper workings and explanation for each and every part and steps with concept and introduction no AI no copy paste remember answer must be in proper format with all working

Br tBuO H3C H3C CH2 H2 Alkyl halides undergo nucleophilic substitution and elimination reactions. When the kinetics of the reaction are measured, if the rate of the reaction is found alkyl halide the reaction is second order. The substitution reaction is thus termed SN2, and the elimination reaction is be dependent upon the concentration of the nucleophile as well as the termed E2. These reactions are bimolecular and take place in a single step. In the SN2 reaction, the nucleophile attacks the a-carbon from the backside and displaces the leaving group with an inversion of configuration occurring at the carbon. In the E2 elimination reaction, strong base removes an acidic hydrogen from the B-carbon and an alkene is formed as the leaving group is expelled from the a-carbon. This elimination follows Zaitsev's rule whereby the more substituted alkene is generally formed. In E2 elimination, both the B-hydrogen and the leaving group must be oriented anti to each other. The same reaction…

Br reagent: Nal solvent: acetone d.

Provide the full mechanism of this SN2 reaction.

1. Reaction mechanism 2. Show sterochemistry

In an E2 mediated elimination reaction of an alkyl halide (H-X) using NaOCH3 as base, which of the following statement is not true? O The reactivity order for alkyl halides (RX) is tertiary secondary> primary. O The rate of reaction = k2 (alkyl halide] [NaOCH₂] O The reaction occurs in a single step. O The rate is independent of the leaving group.

For each of the following reactions give the Major product(s) of the reaction only and statethe mechanism the reaction follows (SN1, SN2, E1, E2).

was reading the organic chemical literature and was surprised to read that this structure reacts with good Lewis/attacker nucleophiles rapidly by the SN1 pathway. Why was Prof. surprised by these data? Explain these data using your knowledge of SN1 pathways. Prof. Me xo Me Me OTS

In addition to the main product (endo product), name a side reaction that might occur in this experiment. i. Draw a reaction scheme of this side reaction.

The following reaction occurs at room temperature in acidic solution, first forming intermediate A, which then rearranges into final product B. i. Show the mechanism for the formation of Intermediate A. ii. Show the mechanism for the rearrangement of A to B (you have seen this before!). iii. Explain why the reaction does NOT occur readily in basic solution using your mechanism from 2.a.1 1. 2. A → -OH B нзод 30°c A + CO₂

Below is the equation for a nucleophilic substitution reaction and some experimental data. CH3CH2Br + CH3COO- ⇌ CH3CH2CO2CH3 + Br- ΔH=-75 kJ/mol Rate = k [CH3CH2Br][CH3COO-] Which reaction energy profile would be the best representative of the data provided?

The reaction shown below does not follow the expected theory. Given what you learnedabout substitution/elimination, what is the expected mechanism this reaction shouldfollow? Suggest why that is not what happens and give the actual product of the reaction.

Provide mechanisms for the two reactions.

pls answer both questions

3. Two reactions are given below. One reaction leads to product and the other does not and the starting material remains unreacted. i) CI NaOCH3 HOCH 3 ii) NaCl OCH 3 HOCH3 a. Draw a complete reaction scheme clearly showing all intermediate products in the space below for the reaction that proceeds to product. b. Draw a reaction coordinate diagram for the forward reaction above from the starting material given to your product showing all intermediates produced along the reaction coordinate. Be sure to label your axes and to think about how the potential energy changes along the reaction coordinate.

Which is the most reactive compound by the SN1 mechanism? O a. Br I CH3CH₂CHCH3 O b. CH3CH₂CH₂CH₂Br O C. (CH3)2CHCH₂Br O d. Br CH3CH₂C(CH3)2

9. The initial rates for the following two elimination reactions were measured under different concentrations of the electrophiles and bases (H2O in the top reaction, KOCH2CH3 in the bottom reaction; all data is presented in the two tables. For each reaction, top and bottom, does the data suggest an El or E2 reaction pathway (rates are all 10* units)? Explain. Write the rate equations for each reaction. Trial Number [R-OCH.] [H,0] Rate (M/s) 0.010 M 0.45 M 9.50 X 10-4 HO 2 0.020 M 0.45 M 1.85 x 10 3 CH,CN, H OCH, 0.22 M 1.85 x 10- 3 0.020 M Trial Number R-Br] [KOCH,CHal Rate (M/s) 6 1.0 M 1.0 M 2.35 X 10 Br 0.50 M 0.50 M 5.9 x 10* + KOCH,CH, CH,CH,OH 3 0.50 M 1.0 M 1.20 x 10 Top Reaction: Bottom Reaction:

Which mechanism is consistent with the reaction below?2NO+2H2→N2+2H2O   1. NO+H2→NOH22. NOH2+NO→N2O2+H23. H2+ N2O2→ N2+H2O   1. NO+H2→N+H2O2. NO+H2→N+H2O   1. NO+H2O→NO2+H22. NO2+H2→N2+H2O   1. 2NO⇄N2O22. N2O2+H2→N2O+H2O3. N2O+H2→N2+H2O