Term Test 2 - Summer 2019
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CHMB42H3 TERM TEST 2 July 18
th
2019, 12:00 pm TIME ALLOWED: 90 MINUTES
Exams must be written in pen for any remarking claims. Write all answers in the spaces provided. Non-programmable calculators and rulers are allowed; no other aids permitted. This exam contains 8 pages: 1 cover sheet (this page), 4 pages of questions (
double sided
), and 3 pages of charts and tables (coloured paper). The charts and tables may be removed from your test and used for rough work; they will be collected, but not be graded. Page 1___________/17 Page 2___________/12 Page 3___________/12 Page 4___________/9 Page 5___________/10 Page 6___________/5 Page 7___________/5 TOTAL___________/70
- 1 - 1)
Indicate whether the following statements are TRUE or FALSE. (8 points) The M+1 peak in a mass spectrum can be used to calculate the number of carbon atoms in the compound. TRUE / FALSE The M+1 peak in a mass spectrum is approximately 1/3 the height of the molecular ion peak for compounds containing a chlorine atom. TRUE / FALSE The most useful nuclei for NMR spectroscopy are spin-active with a quantum spin number of ½
. TRUE / FALSE In the 1
H NMR of 3-methyl-1-butanol, the most upfield signal appears as a triplet. TRUE / FALSE The resonance frequency of a 13
C nucleus is influenced by both nearby nuclei and nearby electrons. TRUE / FALSE In the DEPT-135 of 4-ethylaniline, there are 3 positive signals and 1 negative signal. TRUE / FALSE Stronger bonds vibrate at higher frequencies and therefore absorb IR radiation more intensely. TRUE / FALSE Infrared radiation is absorbed when its energy matches the energy assoc
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TRUE / FALSE 2)
Fill in the table below for the two structures. (4 points) Number of 1
H NMR signals Number of 13
C NMR signals 3)
Assign the signals to the appropriate carbon atoms in the structure below. (5 points) o.CH
at
N
5
i
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- 2 - 4)
Assign the signals to the appropriate hydrogen atoms in the structure below. Integration has not been provided; however you should be able to answer the question without it. (8 points) 5)
Fill in the missing reagents and/or structures for each of the following transformations. Where more than one product can form, show only the major product
. Where the reagents are missing, more than one step may be required to complete the transformation. (16 points, 2 points per box). i
i
UAIHUNDIBAL
2
Hi
3
Hot
Heat
- 3 -
- 4 - 6)
The IR and LRMS for compound X are shown below. Use the table which follows to summarize the key structural information available from these spectra, as well as a brief rationale for each item listed. (9 points) Structural Information Rationale (Be brief! I will only read the first 10 words!)
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- 5 - 7)
Compound X
is a colourless liquid with the molecular formula C
7
H
14
O
2
. Its IR, 1
H NMR and 13
C NMR are provided below. Use the data provided to suggest a reasonable structure for compound X
. For full marks, you must adequately annotate all spectra to support your proposed structure. (10 points) Proposed Structure:
- 6 - 8)
Provide detailed stepwise mechanisms for all steps in the following reactions. a.
(5 points)
- 7 - b.
(5 points) For full marks, include resonance contributors for any charged intermediates. END OF TEST
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SPECTROSCOPIC CORRELATION CHARTS (can be removed from test) 1
H NMR 13
C NMR
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SPECTROSCOPIC CORRELATION CHARTS (can be removed from test) INFRARED SPECTROSCOPY
PERIODIC TABLE (can be removed from test)
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Quèstion 6
Select the statement that is not supported by the following equation:
q=0=(mwater)(Cwater)(ATwater)+ (mmetal)(Cmetal)( ATmetal)
The total change in heat is the sum of the changes in heat of water and a metal.
Energy is conserved.
Energy is transferred between water and a metal.
Energy is lost during a calorimetry experiment.
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The aluminum in a package containing 77 ft" of kitchen foil weighs approximately 19 ounces. Aluminum has a density of 2.70 g/cm. What is the approximate thickness of
the aluminum foil in millimeters? (1 ounce =
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A student calibrated a eudiometer by first recording the mass of the empty eudiometer followed by filling the eudiometer to the 50.00 mL line with deionized water at 22°C and recorded the mass. The mass of water was 49.012 g.
What measured reading from the eudiometer would correspond to a true volume of 47.89mL?
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CENGAGE MINDTAP
Q sea
napter 8: Chemical Composition
AA
e. aluminum sulfate
Answer
51. For each of the following samples of ionic substances, calculate the number of moles and mass
the positive ions present in each sample.
a. 4.25 g of ammonium iodide, NH,I
b. 6.31 moles of ammonium sulfide, (NH4), S
c. 9.71 g of barium phosphide, BagP2
d. 7.63 moles of calcium phosphate, Caz (PO4)2
52. For each of the following ionic substances, calculate the percentage of the overall molar mas
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Determine the volume of a sample of copper in (m³) with a mass of 2.2 x 105 tons and a density of 8.96 g/cm. (1
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purse Home
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e Home
troduction to MasteringChemistry
2 of 15
roduction to Numeric Answers
Part B
When entering large numbers in the answer box, do not use commas. For example, enter 1276400 for the number 1,276,400. Do not enter 1, 276, 400. If you accidentally
enter commas, you will receive feedback as a reminder. Answer the following question by typing the numeric answer into the answer box. What is the sum of 9260 and
3240?
Express your answer numerically to at least three significant figures.
• View Available Hint(s)
Eν ΑΣφ
sum =
Submit
Scientific notation
You may want to enter 367.000 000 in scientific notatinn as 3 67 x 10° There are twn ways to do this
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Dormicdonc Contact l.
Copuriaht 0207 0 Doarcen Education Inc Alrightr rorornd Armr
12:58
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Julie has been asked to measure the concentration of a sample solution using a spectrophotometer. After a first attempt, she realizes that, to make the measurement, she must first dilute the sample solution. Julie transfers 1.3 mL1.3 mL of the sample to a 250 mL250 mL volumetric flask and fills the rest of the flask with water to the 250 mL250 mL line. She then uses the spectrophotometer to measure the concentration of the dilute solution as 5.5×10−5 M.5.5×10−5 M.
What is the concentration of the starting sample solution?
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Question 3
A piece of Na placed into a graduated cylinder of water displaces 22 mL of water. Based on the
given densities, what was the mass of the metal put into the container?
Density (g/cm³)
Metal
titanium 4.50
potassium 0.862
manganese 7.44
lead
sodium
O 21 g
O 13 g
O 17 g
O 9.7 g
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The compound cyclohexanol, C6H120, is a good fuel. It is a liquid at ordinary temperatures. When the liquid is burned, the reaction involved is
2 C6H120(t) + 17 02(g)→12 CO2(g) + 12 H20(g)
The standard enthalpy of formation of liquid cyclohexanol at 25 °C is -348.2 kJ mol-1; other relevant enthalpy of formatton values in kJ mol1 are:
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= oHV
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Express the concentration to three significant figures with the appropriate units.
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A student calibrated a eudiometer by first recording the mass of the empty eudiometer followed by filling the eudiometer to the 50.00 mL line with deionized water at 22°C and recorded the mass. The mass of water was 49.012 g.
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M
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(c) Hominy (lye): [H*] = 3.9 × 10-13
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SPRECALC7 4.7.003.MI. 0/6 Submissions Used
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The pH reading of a sample of each substance is given. Calculate the hydrogen ion concentration of the substance. (Give your answers in scientific notation, correct to one decimal place.)
(a) Vinegar: pH
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[H+] =
10
M
(b) Milk: pH
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%D
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10
M
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b) One component of a mixture being analyzed quantitatively by GC
reacts with the column packing.
c) A radioactive sample being counted repeatedly without any change in
condition yields a slightly different count at each trial.
d) The tip of the pipet used in the analysis is broken.
e) In measuring the same peak heights of a chromatogram, two
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Ab GL B
art 3 SHOW WORK
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Answer
units
▷ Add attachments to support your work
Question 4 (0.5 points)
SHOW YOUR WORK.
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If 35.45 mL of 0.8121 M sodium carbonate solution reacts with excess lead (III)
nitrate solution to form aqueous sodium nitrate and solid lead (III) carbonate, how
many grams of lead (III) carbonate is formed?
On your paper with your name and date:
1. Go from ionic compound name to formula (review Chp 5 as much as needed)
2. Balance the equation (review Chp 7 if needed).
3. Do the calculation showing ALL units, just like I did in solution stoichiometry
lecture.
a #
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DO NOT include units in your answer.
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