Spectroscopy worksheet Orgo 2 (1)
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Name_________________________________ Organic Chem 2 – Spectroscopy Worksheet
1.
One of the following structures is shown in the IR spectra below. Circle which structure would give this spectra.
2.
As in the previous problem, one of the following structures is shown in the IR
spectra below. Circle which structure would give this spectra. Q
3.
How many unique kinds of hydrogens are in the following molecules?
4.
Using IR with NMR:
Propose a structure using the following formula, IR and H-NMR. Use the IR and H-NMR data to explain your answer by referencing specific values.
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5.
Using IR with NMR
Propose a structure using the following formula, IR and H-NMR. Use the IR and H-NMR data to explain your answer by referencing specific values.
6.
Which of the following three structures is represented by the following four spectra? Use the MS, IR, H-NMR and C-NMR to explain your answer by referencing specific values. a.
b.
c. IR:
MS:
H-NMR:
C-NMR:
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Related Documents
Related Questions
Take a look at the reaction in the first image that give two products A and B
The second picture shows the DEPT 90 (TOP) and DEPT 135 (BOTTOM) of the compound that was isolated as only product of this reaction:
In both spectra there are 7 signals between 120 and 140 ppm.
How can you use these DEPT spectra to establish if product A or product B was formed in this reaction? Explain your reasoning.
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refer to image please please label graph and show all work. CALCULATE R VALUE AND EXPLAIN.
will only rate if graph is labelled.
label name of structure too.
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2) The IR spectrum below is of one of the compounds shown. Circle structure that corresponds to the spectrum
and label the peaks you used to make your choice.
Transmittance (%)
OD
D
4000
3000
my
mm
2000
1500
Wavenumber (cm-¹)
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spectrum is consistent with
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DMSO
A. absorption at 3200-3600 cm should disappear
B. absorptions at 3200-3600 cm and 1100 om should disappear
C. absorption at 1100 cm should disappear, a new absorption at 3100 cm should appear
D. absorption at 1720 cm should appear, absorption at 3200-3600 cm should disappear
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O A
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2) On spectra 2 are the mass, IR and 13 C and 1 H NMRspectra of an organic compound.a) From these spectra, determine the structure of the molecule. Rememberto ignore the triad in the 13 C NMR spectrum at 7 ppm that comes from theNMR solvent. b) Draw the structure of the molecule and label each hydrogen with a letter(A, B, C...). Then fill in the peak assignment table below.
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chemical shift
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NAME
PRELAB QUESTIONS
These questions should be answered before coming to lab, and included when you turn in
your lab outline and data sheets.
1. The dissolved compound in a sample has an absorbance value of 0.250. How would you
expect the absorbance to change if:
a. The concentration of the dissolved compound is tripled?
b. The concentration of the dissolved compound is halved?
2. If you have a solution of unknown concentration, describe how you could determine the
approximate concentration.
0.S
a.r
0.1
6.0
0.0
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Steps in Spectral Identification:
•Identify major peaks in IR spectrum, if any.
•Deduce structural fragments for each of the 1H NMR spectral signals.
•Give the structure of the compound
•Assign the signals in the 1H NMR spectra to specific protons
•Assign carbons to the peaks in the 13C NMR spectrum
Step 1. Calculate the degree of unsaturation for the unknown.
Step 2. Determine the functional group from IR
Step 3. Analyzing the MS spectrum
Step 4. Analyzing the 1H NMR spectra
Determine the number of different kinds of protons
Step 5. Analyzing the 13C NMR spectra
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