HP 2021 Chem Paper 2
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The University of Hong Kong *
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Chemistry
Date
Nov 24, 2024
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1
HOI PING CHAMBER OF COMMERCE SECONDARY SCHOOL
Mock Examination 2020/2021
S6 CHEMISTRY Time: 1 hour Name : ________________( ) Class : _____ Block : X1 / X2 / X3 Block No.: ____ CHEMISTRY PAPER 2 Time allowed: 1 hour This paper must be answered in English. INSTRUCTIONS (1)
This paper consists of THREE sections, Section A, Section B and Section C. (Section B is NOT included in this Mock Exam) Attempt ALL questions in any TWO sections. (2)
Write your answers in the Answer Book provided. Start each question (not part of a question) on a new page. (3)
A Periodic Table is printed on page 8 of this Question Paper. Atomic numbers and relative atomic masses of elements can be obtained from the Periodic Table.
2
Section A Industrial Chemistry Answer ALL parts of the question. 1. (a) Answer the following short questions:
(i)
Why is methanol an important compound in the chemical industry? (1 mark) (ii)
Write the chemical equation for the reaction in the production of methanol from syngas, and state the conditions required. (3 marks)
(iii) Chlorine bleach can be manufactured from the products of the electrolysis of brine. Write an equation for the reaction involved. (1 mark) (b)
Ethylene oxide ((CH
2
CH
2
)O) is commonly used as a disinfectant in hospital for sterilizing tools and equipment. It can be synthesized industrially by two methods ─ chlorohydrin process and direct oxidation of ethene.
Chlorohydrin process
CH
2
=CH
2
+ Cl
2
+ H
2
O →
OH
−
CH
2
CH
2
−
Cl + HCl →
(CH
2
CH
2
)O + CaCl
2
+ 2H
2
O
Direct oxidation of ethene
2CH
2
=CH
2
+ O
2
→
2(CH
2
CH
2
)O
(i)
Calculate the atom economy of the two reactions above.
(Relative atomic masses: H = 1.0, C = 12.0, O = 16.0, Cl = 35.5, Ca = 40.1)
(2 marks)
(ii)
Deduce, from TWO perspectives, which method is greener.
(2 marks)
Ca(OH)
2
Ag
3
1. (c) Peroxodisulphate ion can oxidize iodide ion to produce iodine and sulphate ion.
(i)
Write an equation for the reaction of S
2
O
8
2
−
with I
−
.
(1 mark)
(ii) It is found that the reaction proceeds slowly at room conditions. Suggest a possible reason for the low rate (1 mark)
(iii) Three experiments were performed to find the rate constant of the reaction at 25 o
C.
Experiment
[I
−
] (mol dm
-3
)
[S
2
O
8
2
−
] (mol dm
-3
)
Initial rate (mol dm
-3
s
−
1
)
1
0.050
0.006
0.00115
2
0.080
0.004
0.00120
3
0.080
0.005
0.00149
(1) Determine the order of reaction with respect to each reactant.
(2 marks)
(2) Determine the rate constant of the reaction at this temperature.
(1 mark)
(iv)
If the rate of the reaction is found to be doubled when the temperature is raised by 10 o
C, deduce the activation energy of the reaction. (Gas constant = 8.31 JK
-1
mol
-1
) (2 marks)
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4
1.
(c)
(v)
A two-step catalysis of the redox reaction of S
2
O
8
2
−
with I
−
involves the use of Fe
2+
as the catalyst. The first step is given below.
S
2
O
8
2
−
(aq) + 2Fe
2+
(aq) →
2SO
4
2
−
(aq) + 2Fe
3+
(aq)
(1) Write an equation for the second step of the catalysis.
(1 mark)
(2) The following diagram shows a typical Maxwell-Boltzmann distribution curve.
B
represents the activation energy of the reaction between peroxodisulphate ion and iodide ion.
Copy the above curve, mark the activation energy of the catalyesd reaction and label it as ‘
E
’. Hence, explain why the reaction rate is higher when a catalyst is added.
(3 marks)
A
B
Kinetic Number of particles
5
Section C Analytical Chemistry
Answer ALL parts of the question. 3.
(a)
As shown in the diagram below, compound F
formed by carbon, hydrogen and oxygen is burnt in excess oxygen. Anhydrous calcium chloride and calcium oxide are used to absorb water vapour and carbon dioxide respectively during combustion.
(i)
Given that the relative molecular mass of F
is 58.0. Based on the experimental results, deduce the molecular formula of F.
(Relative atomic masses: H = 1.0, C = 12.0, O = 16.0)
(3 marks) (ii)
In order to identify F
, the following tests were carried out. (I)
F
gives a positive result when being tested with 2,4-dinitrophenylhydrazine.
(II)
The infrared spectrum of F
is shown below:
6
3
(a)
(ii)
Characteristic Infra-red Absorption Wavenumber Ranges (Stretching modes)
Bond Compound type Wavenumber range / cm
-1
C
=
C Alkenes 1610 to 1680 C
=
O Aldehydes, ketones, carboxylic acids and derivatives 1680 to 1800 C
≡
C Alkynes 2070 to 2250 C
≡
N Nitriles 2200 to 2280 O
-
H Acids (hydrogen-bonded) 2500 to 3300 C
-
H Alkanes, alkenes, arenes 2840 to 3095 O
-
H Alcohols, phenols (hydrogen-bonded) 3230 to 3670 N
-
H Amines 3350 to 3500 (1) What is the observation for the positive result of the test with 2,4-dinitrophenylhydrazine?
(1 mark) (2) Based on the above information, deduce two possible structures of F
. (4 marks) (iii) The mass spectrum of F
shows strong signals at m/z = 58 and 43. Deduce the structure of F
. (2 marks) (b)
A student was given four bottles of solutions W, X, Y and Z. Each of them is one of the following solutions:
K
2
CO
3,
MgSO
4
, HCl, Pb(NO
3
)
2
A series of tests were performed to identify the solution in each bottle. In each test, two of the solutions were mixed together and the observation was tabulated below:
Solutions being mixed
Observation
W+X
A white precipitate formed.
W+Y
A white precipitate formed.
W+Z
A white precipitate formed.
X+Y
A white precipitate formed.
X+Z
Colourless gas bubbles evolved.
Y+Z
No observable change.
Based on the above observations, what are the solution in each of the four bottles?
(4 marks)
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7
3. (c) Burning sodium in air produces a mixture of sodium oxide (Na
2
O) and sodium peroxide (Na
2
O
2
). The percentage by mass of sodium peroxide in the oxide mixture can be determined by the following experiments. Step 1: 0.50 g of a sample oxide mixture is completely dissolved in distilled water. Na
2
O(s) + H
2
O(l) →
2NaOH(aq) Na
2
O
2
(s) + 2H
2
O(l) →
2NaOH(aq) + H
2
O
2
(l) Step 2: The solution is acidified and is titrated with 0.020 M potassium permanganate solution. 33.40 cm
3
of 0.020 M KMnO
4
is required to react with all hydrogen peroxide (H
2
O
2
) formed from sodium peroxide. (i) What is the flame colour observed when sodium is burnt in air? (1 mark)
(ii) Explain why it is NOT necessary to add any indicator in the titration. (1 mark)
(iii) (1) Hydrogen peroxide may react with KMnO
4 to give oxygen gas and hydrogen ion
. Write an ionic equation for the reaction involved in the titration. (2)
Calculate the percentage by mass of sodium peroxide in the sample oxide mixture.
(4 marks) END OF PAPER
8
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